Peculiarities of nucleation in large, deeply supercooled liquid clusters

被引：6

作者：

Bartell, LS ^{[1
]}

Chushak, YG ^{[1
]}

Huang, JF ^{[1
]}

机构：

[1] Univ Michigan, Dept Chem, Ann Arbor, MI 48109 USA

来源：

ATMOSPHERIC RESEARCH | 2003年 / 65卷 / 3-4期

基金：

美国国家科学基金会;

关键词：

nucleation; liquid clusters; supercoolings;

D O I：

10.1016/S0169-8095(02)00147-3

中图分类号：

P4 [大气科学（气象学）];

学科分类号：

0706 ; 070601 ;

摘要：

Characteristic differences between the nucleation of solids in bulk liquids and in liquid clusters are identified in computer simulations, and the reasons for these differences are discussed. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：153 / 160

页数：8

共 14 条

[1] Granulation, Phase Change, and Microstructure - Kinetics of Phase Change. III [J].

Avrami, M .

JOURNAL OF CHEMICAL PHYSICS, 1941, 9 (02) :177-184

[2] Kinetics of phase change I - General theory [J].

Avrami, M .

JOURNAL OF CHEMICAL PHYSICS, 1939, 7 (12) :1103-1112

[3]

Avrami M., 1940, J CHEM PHYS, V8, P212

[4] CORE AND SURFACE-PROPERTIES OF BCC CLUSTERS OF SEF6 AND DYNAMICS OF HOMOGENEOUS NUCLEATION TO MONOCLINIC PHASE - A MOLECULAR-DYNAMICS STUDY [J].

BARTELL, LS ;

XU, SM .

JOURNAL OF PHYSICAL CHEMISTRY, 1995, 99 (26) :10446-10453

[5] Structure and transformation: Large molecular clusters as models of condensed matter [J].

Bartell, LS .

ANNUAL REVIEW OF PHYSICAL CHEMISTRY, 1998, 49 :43-72

[6] Crystal nucleation and growth in large clusters of SeF6 from molecular dynamics simulations [J].

Chushak, Y ;

Bartell, LS .

JOURNAL OF PHYSICAL CHEMISTRY A, 2000, 104 (41) :9328-9336

[7]

Gibbs J.W., 1876, Am.J. Sci, V3, P108, DOI DOI 10.2475/AJS.S3-16.96.441

[8] Comparison of experiments and modern theories of crystal nucleation [J].

Granasy, L ;

Igloi, F .

JOURNAL OF CHEMICAL PHYSICS, 1997, 107 (09) :3634-3644

[9] FREE-ENERGIES OF SOLID-LIQUID INTERFACES [J].

JONES, DRH .

JOURNAL OF MATERIALS SCIENCE, 1974, 9 (01) :1-17

[10]

ROWLINSON JS, 1989, MOL THEORY CAPILLARI, P180

← 1 2 →