Enantioselective desymmetrizing palladium catalyzed carbonylation reactions: the catalytic asymmetric synthesis of quaternary carbon center containing 1,3-dienes

被引：14

作者：

Byrne, Simon J. ^{[2
]}

Fletcher, Anthony J. ^{[1
]}

Hebeisen, Paul ^{[3
]}

Willis, Michael C. ^{[1
]}

机构：

[1] Univ Oxford, Dept Chem, Chem Res Lab, Oxford OX1 3TA, England

[2] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England

[3] F Hoffmann La Roche Ltd, Discovery Chem, Pharmaceut Res Basel, CH-4070 Basel, Switzerland

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2010年 / 8卷 / 04期

基金：

英国工程与自然科学研究理事会;

关键词：

ARYL; CONSTRUCTION; CYCLIZATION; ALKYLATION;

D O I：

10.1039/b923186b

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A desymmetrization protocol has been used to develop a palladium catalyzed enantioselective carbonylation process. Achiral cyclic bis-alkenyltriflates are converted to their corresponding monoester derivatives with selectivities of up to 96% ee.

引用

页码：758 / 760

页数：3

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