Amine-Ligated Approach for the Synthesis of Extra-Large-Pore Zinc Phosphites with qtz-h and bnn Topologies

被引：19

作者：

Wang, Kangcai ^{[1
]}

Bian, Yixuan ^{[1
]}

Li, Jing ^{[1
]}

Xu, Dingguo ^{[1
]}

Lin, Zhien ^{[1
]}

机构：

[1] Sichuan Univ, Coll Chem, Chengdu 610064, Peoples R China

来源：

INORGANIC CHEMISTRY | 2016年 / 55卷 / 08期

关键词：

24-RING CHANNELS; BERYLLIUM PHOSPHITE; METAL PHOSPHITE; HELICAL CHAINS; FRAMEWORK; CHEMISTRY;

D O I：

10.1021/acs.inorgchem.6b00589

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Presented here are two open-framework zinc phosphites, namely, Zn(dabco)(0.5)(HPO3) (SCU-18) and Zn-4(Hdabco)(2)(CH3COO)(2)(HPO3)(4) (SCU-20), where dabco = 1,4-diazabicyclo [2.2.2] octane. SCU-18 features a rare 3-connected inorganic skeleton with a chiral qtz-h topology. It contains 18-membered-ring (18 MR) channels displaying porosity and, second-harmonic generation response. SCU-20 has a bnn topology containing large 20 MR channels that shows a strong blue emission as a result of excitation at 375 nm.

引用

页码：3727 / 3729

页数：3

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