Silica gel-mediated rearrangement of allylic acetates. Application to the synthesis of 1,3-enynes

被引：31
|
作者：
Serra-Muns, Anna [1 ]
Guerinot, Amandine [1 ]
Reymond, Sebastien [1 ]
Cossy, Janine [1 ]
机构：
[1] ESPCI ParisTech, CNRS, UMR 7084, Chim Organ Lab, F-75231 Paris 05, France
来源：
CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 23期
关键词：
STEREOSELECTIVE-SYNTHESIS; PALLADIUM(II); ISOMERIZATION; CONVERSION;
D O I：
10.1039/c0cc00035c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Silica gel was found to efficiently promote the rearrangement of allylic acetates into their most stable regioisomers under microwave irradiation. The reaction is easy to perform and eco-friendly. This method was applied to the metal-free synthesis of 1,3-enynes.
引用
收藏
页码：4178 / 4180
页数：3
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