Water-Processable Self-Doped Conducting Polymers via Direct (Hetero)arylation Polymerization

被引：40

作者：

Beaumont, Catherine ^{[1
]}

Turgeon, Josyane ^{[1
]}

Idir, Mael ^{[1
]}

Neusser, David ^{[2
]}

Lapointe, Rosalie ^{[1
]}

Caron, Samuel ^{[1
]}

Dupont, William ^{[1
]}

D'Astous, Dominic ^{[1
]}

Shamsuddin, Sareeha ^{[3
]}

Hamza, Sarah ^{[3
]}

Landry, Eric ^{[3
]}

Ludwigs, Sabine ^{[2
]}

Leclerc, Mario ^{[1
]}

机构：

[1] Univ Laval, Dept Chim, Quebec City, PQ G1V 0A6, Canada

[2] Univ Stuttgart, Inst Polymer Chem, IPOC Funct Polymers, D-70569 Stuttgart, Germany

[3] Polyanalytik, London, ON N6G 4X8, Canada

来源：

MACROMOLECULES | 2021年 / 54卷 / 12期

基金：

加拿大自然科学与工程研究理事会;

关键词：

CONJUGATED POLYMERS; PEDOTPSS; POLY(3,4-ETHYLENEDIOXYTHIOPHENE); 3,4-ETHYLENEDIOXYTHIOPHENE; POLYTHIOPHENE; DEVICES;

D O I：

10.1021/acs.macromol.1c00847

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The synthesis of water-processable self-doped polymers has been achieved by direct (hetero)arylation polymerization (DHAP) using water as a cosolvent. The introduction of a counterion covalently attached to the backbone of the polymers enhanced their solubility and the stability of the solutions. Those polymers have shown air-stable electrical conductivities up to 50 S cm(-1) without the use of any post-treatment. The good water processability of these conducting polymers is promising for printed electronics in a wide range of applications.

引用

收藏

页码：5464 / 5472

页数：9

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