Chiral Kagome Network from Thiacalix[4]arene Tetrasulfonate at the Interface of Aqueous Solution/Au(111) Surface: An in Situ Electrochemical Scanning Tunneling Microscopy Study

被引:52
作者
Chen, Ting
Chen, Qing
Zhang, Xu
Wang, Dong [1 ]
Wan, Li-Jun
机构
[1] Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China
基金
中国国家自然科学基金;
关键词
MOLECULAR CRYSTALLIZATION; AU(111); FULLERENE; SULFATE; ADLAYER; COMPLEX; ARRAYS; STM;
D O I
10.1021/ja101598p
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A chiral Kagome network was fabricated at an aqueous solution/Au(111) interface by using a complicated stereo supramolecule thiacalix[4]arene tetrasulfonate as a building block. It opens the possibility to construct a 2D nanoporous network by various functional supramolecules and shows potential application in host-guest chemistry as well as chiral resolution.
引用
收藏
页码:5598 / +
页数:3
相关论文
共 22 条
[1]   Metal sulfonatocalix[4,5]arene complexes: bi-layers, capsules, spheres, tubular arrays and beyond [J].
Atwood, JL ;
Barbour, LJ ;
Hardie, MJ ;
Raston, CL .
COORDINATION CHEMISTRY REVIEWS, 2001, 222 :3-32
[2]   Directing two-dimensional molecular crystallization using guest templates [J].
Blunt, Matthew ;
Lin, Xiang ;
Gimenez-Lopez, Maria del Carmen ;
Schroder, Martin ;
Champness, Neil R. ;
Beton, Peter H. .
CHEMICAL COMMUNICATIONS, 2008, (20) :2304-2306
[3]   The adsorption of sulfate and phosphate on Au(111) and Au(100) electrodes:: an in situ STM study [J].
Cuesta, A ;
Kleinert, M ;
Kolb, DM .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2000, 2 (24) :5684-5690
[4]   Molecular geometry directed Kagome and honeycomb networks: Toward two-dimensional crystal engineering [J].
Furukawa, S ;
Uji-i, H ;
Tahara, K ;
Ichikawa, T ;
Sonoda, M ;
De Schryver, FC ;
Tobe, Y ;
De Feyter, S .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (11) :3502-3503
[5]   Geometrically frustrated magnetic materials [J].
Greedan, JE .
JOURNAL OF MATERIALS CHEMISTRY, 2001, 11 (01) :37-53
[6]  
GUTSCHE DC, 1998, CALIXARENES REVISITE
[7]   Supramolecular nano networks formed by molecular-recognition-directed self-assembly of ditopic calix[5]arene and dumbbell [60]fullerene [J].
Haino, T ;
Matsumoto, Y ;
Fukazawa, Y .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (25) :8936-8937
[8]   Dichotomous Array of Chiral Quantum Corrals by a Self-Assembled Nanoporous Kagome Network [J].
Klappenberger, Florian ;
Kuehne, Dirk ;
Krenner, Wolfgang ;
Silanes, Inaki ;
Arnau, Andres ;
Javier Garcia de Abajo, F. ;
Klyatskaya, Svetlana ;
Ruben, Mario ;
Barth, Johannes V. .
NANO LETTERS, 2009, 9 (10) :3509-3514
[9]   Inclusion behavior of water-soluble thiacalix- and calix[4]arenes towards substituted benzenes in aqueous solution [J].
Kon, N ;
Ki, N ;
Miyano, S .
ORGANIC & BIOMOLECULAR CHEMISTRY, 2003, 1 (04) :751-755
[10]   Complex formation between water-soluble sulfonated calixarenes and C60 fullerene [J].
Kunsági-Máté, S ;
Szabó, K ;
Bitter, I ;
Nagy, G ;
Kollár, L .
TETRAHEDRON LETTERS, 2004, 45 (07) :1387-1390