Layer Controllable Graphene Using Graphite Intercalation Compounds with Different Stage Numbers through Li Conversion Reaction

被引：10

作者：

Wang, Fei ^{[1
,2
,3
]}

Chen, Guorui ^{[4
,5
]}

Li, Wei ^{[1
,2
,3
]}

Wang, Yonggang ^{[1
,2
,3
]}

Wang, Congxiao ^{[1
,2
,3
]}

Zhang, Yuanbo ^{[4
,5
]}

Xia, Yongyao ^{[1
,2
,3
]}

机构：

[1] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China

[2] Fudan Univ, Shanghai Key Lab Mol Catalysis & Innovat Mat, Inst New Energy, Shanghai 200433, Peoples R China

[3] Fudan Univ, iChEM Collaborat Innovat Ctr Chem Energy Mat, Shanghai 200433, Peoples R China

[4] Fudan Univ, State Key Lab Surface Phys, Shanghai 200433, Peoples R China

[5] Fudan Univ, Dept Phys, Shanghai 200433, Peoples R China

来源：

ADVANCED MATERIALS INTERFACES | 2016年 / 3卷 / 03期

基金：

中国国家自然科学基金;

关键词：

HIGH-YIELD; ELECTROCHEMICAL EXPANSION; FILMS; EXFOLIATION; PHASE; GROWTH; FLAKES; OXIDE; BI;

D O I：

10.1002/admi.201500496

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Graphene with controlled stacking numbers and fewer defects is synthesized through an electrochemical approach using metal chloride graphite intercalation compounds (GICs) via a lithium conversion reaction. Using GICs with different stage numbers as precursors, graphene with different layers is successfully obtained. The mobility estimated from the transport measurement is around 4000 cm2 V-1 s-1, which is comparable to the micromechanically cleaved bilayer graphene. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页数：5

共 36 条

[1] INTERCALATION COMPOUNDS OF GRAPHITE [J].

DRESSELHAUS, MS ;

DRESSELHAUS, G .

ADVANCES IN PHYSICS, 1981, 30 (02) :139-326

[2] INTERCALATION COMPOUNDS OF GRAPHITE [J].

DRESSELHAUS, MS ;

DRESSELHAUS, G .

ADVANCES IN PHYSICS, 1981, 30 (02) :139-326

[3] Large-area ultrathin films of reduced graphene oxide as a transparent and flexible electronic material [J].

Eda, Goki ;

Fanchini, Giovanni ;

Chhowalla, Manish .

NATURE NANOTECHNOLOGY, 2008, 3 (05) :270-274

[4]

Emtsev KV, 2009, NAT MATER, V8, P203, DOI [10.1038/NMAT2382, 10.1038/nmat2382]

[5] Raman spectrum of graphene and graphene layers [J].

Ferrari, A. C. ;

Meyer, J. C. ;

Scardaci, V. ;

Casiraghi, C. ;

Lazzeri, M. ;

Mauri, F. ;

Piscanec, S. ;

Jiang, D. ;

Novoselov, K. S. ;

Roth, S. ;

Geim, A. K. .

PHYSICAL REVIEW LETTERS, 2006, 97 (18)

[6] Repeated growth and bubbling transfer of graphene with millimetre-size single-crystal grains using platinum [J].

Gao, Libo ;

Ren, Wencai ;

Xu, Huilong ;

Jin, Li ;

Wang, Zhenxing ;

Ma, Teng ;

Ma, Lai-Peng ;

Zhang, Zhiyong ;

Fu, Qiang ;

Peng, Lian-Mao ;

Bao, Xinhe ;

Cheng, Hui-Ming .

NATURE COMMUNICATIONS, 2012, 3

[7] The rise of graphene [J].

Geim, A. K. ;

Novoselov, K. S. .

NATURE MATERIALS, 2007, 6 (03) :183-191

[8] Electronic transport properties of individual chemically reduced graphene oxide sheets [J].

Gomez-Navarro, Cristina ;

Weitz, R. Thomas ;

Bittner, Alexander M. ;

Scolari, Matteo ;

Mews, Alf ;

Burghard, Marko ;

Kern, Klaus .

NANO LETTERS, 2007, 7 (11) :3499-3503

[9] High-yield production of graphene by liquid-phase exfoliation of graphite [J].

Hernandez, Yenny ;

Nicolosi, Valeria ;

Lotya, Mustafa ;

Blighe, Fiona M. ;

Sun, Zhenyu ;

De, Sukanta ;

McGovern, I. T. ;

Holland, Brendan ;

Byrne, Michele ;

Gun'ko, Yurii K. ;

Boland, John J. ;

Niraj, Peter ;

Duesberg, Georg ;

Krishnamurthy, Satheesh ;

Goodhue, Robbie ;

Hutchison, John ;

Scardaci, Vittorio ;

Ferrari, Andrea C. ;

Coleman, Jonathan N. .

NATURE NANOTECHNOLOGY, 2008, 3 (09) :563-568

[10] PREPARATION OF GRAPHITIC OXIDE [J].

HUMMERS, WS ;

OFFEMAN, RE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (06) :1339-1339

← 1 2 3 4 →