Functionalization with MXene (Ti3C2) Enhances the Wettability and Shear Strength of Carbon Fiber-Epoxy Composites

被引:96
作者
Liu, Lu [1 ]
Ying, Guobing [1 ]
Hu, Cong [1 ]
Zhang, Kaicheng [1 ]
Ma, Fengchen [1 ]
Su, Lin [1 ]
Zhang, Chen [1 ]
Wang, Cheng [1 ]
机构
[1] Hohai Univ, Coll Mech & Mat, Dept Mat Sci & Engn, Nanjing 211100, Jiangsu, Peoples R China
基金
中国国家自然科学基金;
关键词
MXene; carbon fiber; microstructure; interfacial properties; composites; GRAPHENE OXIDE; INTERFACIAL PROPERTIES; MECHANICAL-PROPERTIES; THERMAL-PROPERTIES; SURFACE; REINFORCEMENT; TENSILE; NANOCOMPOSITES; NANOPARTICLES; NANOTUBES;
D O I
10.1021/acsanm.9b01127
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
MXene is a two-dimensional transition metal carbide or carbonitride with graphene-like 2D morphology and high surface activity, which are useful features in energy storage, catalysis, and adsorption. However, only a handful of structural applications have so far been reported. In this study, functionalization of a carbon fiber (CF) was achieved by MXene (Ti3C2) to improve the CF surface wettability. The results showed that functionalization of MXene not only changed the CF surface topography and increased the mechanical engagement effect during debonding but also enhanced the surface activity of carbon fibers. The interfacial shear strength increased by 186% when compared with nonfunctionalized specimens. A possible interfacial enhancement mechanism was proposed to provide a future roadmap for surface modification of carbon fibers.
引用
收藏
页码:5553 / 5562
页数:19
相关论文
共 49 条
[1]   Interaction of Polar and Nonpolar Polyfluorenes with Layers of Two-Dimensional Titanium Carbide (MXene): Intercalation and Pseudocapacitance [J].
Boota, Muhammad ;
Pasini, Mariacecilia ;
Galeotti, Francesco ;
Porzio, William ;
Zhao, Meng-Qiang ;
Halim, Joseph ;
Gogotsi, Yury .
CHEMISTRY OF MATERIALS, 2017, 29 (07) :2731-2738
[2]   Enhanced thermal properties of poly(vinylidene fluoride) composites with ultrathin nanosheets of MXene [J].
Cao, Yong ;
Deng, Qihuang ;
Liu, Zhiduo ;
Shen, Dianyu ;
Wang, Ting ;
Huang, Qing ;
Du, Shiyu ;
Jiang, Nan ;
Lin, Cheng-Te ;
Yu, Jinhong .
RSC ADVANCES, 2017, 7 (33) :20494-20501
[3]  
CAREY M, 2017, THESIS
[4]   Materials science - Making strong fibers [J].
Chae, Han Gi ;
Kumar, Satish .
SCIENCE, 2008, 319 (5865) :908-909
[5]   Effects of bimetallic Ce/Fe nanoparticles on the desulfurization of thiophenes using activated carbon [J].
Danmaliki, Gaddafi I. ;
Saleh, Tawfik A. .
CHEMICAL ENGINEERING JOURNAL, 2017, 307 :914-927
[6]   First-Principle Study of Hydroxyl Functional Groups on Pristine, Defected Graphene, and Graphene Epoxide [J].
Ghaderi, Nahid ;
Peressi, Maria .
JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (49) :21625-21630
[7]   Conductive two-dimensional titanium carbide 'clay' with high volumetric capacitance [J].
Ghidiu, Michael ;
Lukatskaya, Maria R. ;
Zhao, Meng-Qiang ;
Gogotsi, Yury ;
Barsoum, Michel W. .
NATURE, 2014, 516 (7529) :78-U171
[8]   Transparent Conductive Two-Dimensional Titanium Carbide Epitaxial Thin Films [J].
Halim, Joseph ;
Lukatskaya, Maria R. ;
Cook, Kevin M. ;
Lu, Jun ;
Smith, Cole R. ;
Naslund, Lars-Ake ;
May, Steven J. ;
Hultman, Lars ;
Gogotsi, Yury ;
Eklund, Per ;
Barsoum, Michel W. .
CHEMISTRY OF MATERIALS, 2014, 26 (07) :2374-2381
[9]   Chemically-Modulated Photoluminescence of Graphene Oxide for Selective Detection of Neurotransmitter by "Turn-On" Response [J].
Jeon, Su-Ji ;
Kwak, Seon-Yeong ;
Yim, DaBin ;
Ju, Jong-Min ;
Kim, Jong-Ho .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (31) :10842-10845
[10]   Enhanced mechanical properties of short carbon fiber reinforced polyethersulfone composites by graphene oxide coating [J].
Li, Fei ;
Liu, Yu ;
Qu, Cheng-Bing ;
Xiao, Hong-Mei ;
Hua, Yang ;
Sui, Guo-Xin ;
Fu, Shao-Yun .
POLYMER, 2015, 59 :155-165