Comparison of tungsten films grown by CVD and hot-wire assisted atomic layer deposition in a cold-wall reactor

被引:15
作者
Yang, Mengdi [1 ]
Aarnink, Antonius A. I. [1 ]
Kovalgin, Alexey Y. [1 ]
Gravesteijn, Dirk. J. [1 ]
Wolters, Rob A. M. [1 ]
Schmitz, Jurriaan [1 ]
机构
[1] Univ Twente, MESA Inst Nanotechnol, POB 217, NL-7500 AE Enschede, Netherlands
来源
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A | 2016年 / 34卷 / 01期
关键词
CHEMICAL-VAPOR-DEPOSITION; W THIN-FILMS; BETA-TUNGSTEN; AMORPHOUS-SILICON; HYDROGEN; PHASE; PLASMA; DISSOCIATION; NITRIDE; ALD;
D O I
10.1116/1.4936387
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
In this work, the authors developed hot-wire assisted atomic layer deposition (HWALD) to deposit tungsten (W) with a tungsten filament heated up to 1700-2000 degrees C. Atomic hydrogen (at-H) was generated by dissociation of molecular hydrogen (H-2), which reacted with WF6 at the substrate to deposit W. The growth behavior was monitored in real time by an in situ spectroscopic ellipsometer. In this work, the authors compare samples with tungsten grown by either HWALD or chemical vapor deposition (CVD) in terms of growth kinetics and properties. For CVD, the samples were made in a mixture of WF6 and molecular or atomic hydrogen. Resistivity of the WF6-H-2 CVD layers was 20 mu Omega.cm, whereas for the WF6-at-H-CVD layers, it was 28 mu Omega.cm. Interestingly, the resistivity was as high as 100 mu Omega.cm for the HWALD films, although the tungsten films were 99% pure according to x-ray photoelectron spectroscopy. X-ray diffraction reveals that the HWALD W was crystallized as beta-W, whereas both CVD films were in the alpha-W phase. (C) 2015 American Vacuum Society.
引用
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页数:10
相关论文
共 55 条
[1]  
Aarnink A. A. I., 2013, U. S. patent, Patent No. [20130337653 A1, 20130337653]
[2]   DEGRADATION OF THE THERMAL OXIDE OF THE SI/SIO2AL SYSTEM DUE TO VACUUM-ULTRAVIOLET IRRADIATION [J].
AFANAS'EV, VV ;
DENIJS, JMM ;
BALK, P ;
STESMANS, A .
JOURNAL OF APPLIED PHYSICS, 1995, 78 (11) :6481-6490
[3]  
Allen F., 1995, INTERNATIONAL TABLES, VC
[4]  
Bartl A., 1997, THESIS TU VIENNA
[5]   SUPERCONDUCTIVITY IN BETA-TUNGSTEN FILMS [J].
BASAVAIAH, S ;
POLLACK, SR .
JOURNAL OF APPLIED PHYSICS, 1968, 39 (12) :5548-+
[6]   MICROSTRUCTURE AND ELECTRICAL CHARACTERISTICS OF TUNGSTEN AND WSIX CONTACTS TO GAAS [J].
BASILE, DP ;
BAUER, CL ;
MAHAJAN, S ;
MILNES, AG ;
JACKSON, TN ;
DEGELORMO, J .
MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 1991, 10 (03) :171-179
[7]   DIRECT-CURRENT-MAGNETRON DEPOSITION OF MOLYBDENUM AND TUNGSTEN WITH RF-SUBSTRATE BIAS [J].
BENSAOULA, A ;
WOLFE, JC ;
IGNATIEV, A ;
FONG, FO ;
LEUNG, TS .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A-VACUUM SURFACES AND FILMS, 1984, 2 (02) :389-392
[8]  
Bystrova S., 2004, THESIS U TWENTE
[9]   HYDROGEN REDUCTION OF TUNGSTEN TRIOXIDE [J].
CHARLTON, MG .
NATURE, 1952, 169 (4290) :109-110
[10]   HYDROGEN REDUCTION OF TUNGSTEN OXIDES [J].
CHARLTON, MG .
NATURE, 1954, 174 (4432) :703-703