The Diels-Alder Reaction in Steroid Synthesis

被引：47
|
作者：
Mackay, Emily G. [1 ]
Sherburn, Michael S. [1 ]
机构：
[1] Australian Natl Univ, Res Sch Chem, Canberra, ACT 0200, Australia
来源：
SYNTHESIS-STUTTGART | 2015年 / 47卷 / 01期
基金：
澳大利亚研究理事会;
关键词：
steroids; Diels-Alder reaction; total synthesis; cycloadditions; synthetic methodology; 1ST TOTAL-SYNTHESIS; CONDENSED RING COMPOUNDS; STEREOSELECTIVE TOTAL-SYNTHESIS; FISCHER CARBENE COMPLEXES; FORMAL TOTAL-SYNTHESIS; INTRAMOLECULAR 2-ALKYNE ANNULATIONS; ENANTIOSELECTIVE TOTAL-SYNTHESIS; ASYMMETRIC TOTAL-SYNTHESIS; RUTHENIUM PNNP COMPLEXES; ONE-STEP CONSTRUCTION;
D O I：
10.1055/s-0034-1378676
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
This review explores the myriad ways in which the Diels-Alder reaction has been employed in the construction of the tetracyclic steroid nucleus. A systematic analysis of possible approaches highlights both the synthetic versatility of this ubiquitous reaction and also opportunities for new routes to fused tetracarbocyclic steroid frameworks.
引用
收藏
页码：1 / 21
页数：21
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