Ruthenium-catalyzed hydrosilylation of C=N bond in benzothiazole

被引：7

作者：

Kucinski, Krzysztof ^{[1
]}

Hreczycho, Grzegorz ^{[1
]}

机构：

[1] Adam Mickiewicz Univ, Fac Chem, Umultowska 89b, PL-61614 Poznan, Poland

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2017年 / 846卷

关键词：

Hydrosilylation; Benzothiazole; Silanes; Homogeneous catalysis; N-silylated products; SI-H BONDS; CARBONYL; COMPLEXES; REDUCTION; LIGAND; DISPROPORTIONATION; TRIETHOXYSILANE; CHEMISTRY; ARYLATION; PYRIDINE;

D O I：

10.1016/j.jorganchem.2017.07.007

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Various tertiary hydrosilanes are shown to be compatible with ruthenium-catalyzed hydrosilylation of carbon-nitrogen double bond in benzothiazole. The addition reaction was successfully performed by using a catalytic amount of Ru-3(CO)(12). The products were isolated and characterized by IR, H-1 NMR, C-13 NMR, Si-29 NMR, HRMS and MS analysis. This is the first example for the catalytic hydrosilylation of benzothiazole. (C) 2017 Elsevier B.V. All rights reserved.

引用

收藏

页码：321 / 325

页数：5

相关论文

共 50 条

[41] Photoinduced Ruthenium-Catalyzed meta-C-H Glycosylation [J].

Poehlmann, Julia ;

Yuan, Binbin ;

Purushothaman, Rajeshwaran ;

Wu, Jun ;

Ackermann, Lutz .

ACS CATALYSIS, 2025, 15 (12) :10542-10549

[42] Ruthenium-Catalyzed ortho C-H Borylation of Arylphosphines [J].

Fukuda, Kazuishi ;

Iwasawa, Nobuharu ;

Takaya, Jun .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2019, 58 (09) :2850-2853

[43] Ruthenium-Catalyzed Cascade N- and C(3)-Dialkylation of Cyclic Amines with Alcohols Involving Hydrogen Autotransfer Processes [J].

Sundararaju, Basker ;

Tang, Zhou ;

Achard, Mathieu ;

Sharma, Gangavaram V. M. ;

Toupet, Loic ;

Bruneau, Christian .

ADVANCED SYNTHESIS & CATALYSIS, 2010, 352 (18) :3141-3146

[44] Ruthenium catalyzed selective hydrosilylation of aldehydes [J].

Chatterjee, Basujit ;

Gunanathan, Chidambaram .

CHEMICAL COMMUNICATIONS, 2014, 50 (07) :888-890

[45] Ruthenium-catalyzed ortho alkenylation of aromatic nitriles with activated alkenes via C-H bond activation [J].

Reddy, Mallu Chenna ;

Jeganmohan, Masilamani .

CHEMICAL COMMUNICATIONS, 2015, 51 (53) :10738-10741

[46] Synthesis of m-Alkylphenols via a Ruthenium-Catalyzed C-H Bond Functionalization of Phenol Derivatives [J].

Li, Gang ;

Gao, Panpan ;

Lv, Xulu ;

Qu, Chen ;

Yan, Qngkai ;

Wang, Ya ;

Yang, Suling ;

Wang, Junjie .

ORGANIC LETTERS, 2017, 19 (10) :2682-2685

[47] Mechanistic Insights into Grubbs-Type Ruthenium-Complex-Catalyzed Intramolecular Alkene Hydrosilylation: Direct σ-Bond Metathesis in the Initial Stage of Hydrosilylation [J].

Bokka, Apparao ;

Hua, Yuanda ;

Berlin, Adam S. ;

Jeon, Junha .

ACS CATALYSIS, 2015, 5 (06) :3189-3195

[48] Regioselective Formation of α-Vinylpyrroles from the Ruthenium-Catalyzed Coupling Reaction of Pyrroles and Terminal Alkynes Involving C-H Bond Activation [J].

Gao, Ruili ;

Yi, Chae S. .

JOURNAL OF ORGANIC CHEMISTRY, 2010, 75 (09) :3144-3146

[49] Photo-Induced Ruthenium-Catalyzed C-H Arylations at Ambient Temperature [J].

Korvorapun, Korkit ;

Struwe, Julia ;

Kuniyil, Rositha ;

Zangarelli, Agnese ;

Casnati, Anna ;

Waeterschoot, Marjo ;

Ackermann, Lutz .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2020, 59 (41) :18103-18109

[50] Hydrosilylation reaction of ethylene with triethoxysilane catalyzed by ruthenium halides and promoted by cuprous halides [J].

Liu, Ling ;

Li, Xiaonian ;

Dong, Hong ;

Wu, Chuan .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2013, 745 :454-459

← 1 2 3 4 5 →