Ruthenium-catalyzed hydrosilylation of C=N bond in benzothiazole

被引：7
作者：
Kucinski, Krzysztof [1 ]
Hreczycho, Grzegorz [1 ]
机构：
[1] Adam Mickiewicz Univ, Fac Chem, Umultowska 89b, PL-61614 Poznan, Poland
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2017年 / 846卷
关键词：
Hydrosilylation; Benzothiazole; Silanes; Homogeneous catalysis; N-silylated products; SI-H BONDS; CARBONYL; COMPLEXES; REDUCTION; LIGAND; DISPROPORTIONATION; TRIETHOXYSILANE; CHEMISTRY; ARYLATION; PYRIDINE;
D O I：
10.1016/j.jorganchem.2017.07.007
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Various tertiary hydrosilanes are shown to be compatible with ruthenium-catalyzed hydrosilylation of carbon-nitrogen double bond in benzothiazole. The addition reaction was successfully performed by using a catalytic amount of Ru-3(CO)(12). The products were isolated and characterized by IR, H-1 NMR, C-13 NMR, Si-29 NMR, HRMS and MS analysis. This is the first example for the catalytic hydrosilylation of benzothiazole. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码：321 / 325
页数：5
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