A novel two-dimensional organic-inorganic hybrid compound with a (4,6)-lattice-type network:: {[Co(H2O)2][Co2(phen)2(btc)2]}n(btc = benzene-1,2,4-tricarboxylate)

被引：9
作者：
Hao, N
Liu, FC
Wang, EB [1 ]
Huang, RD
Li, YG
Hu, CW
机构：
[1] NE Normal Univ, Dept Chem, Inst Polyoxometalate Chem, Changchun 130024, Jilin, Peoples R China
[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
[3] Beijing Inst Technol, Dept Chem, Sch Chem Engn & Mat, Beijing 100081, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2003年 / 6卷 / 06期
基金：
中国国家自然科学基金;
关键词：
coordination polymer; metal-organic network; hydrothermal synthesis; crystal structure;
D O I：
10.1016/S1387-7003(03)00094-7
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new organic-inorganic hybrid compound {[Co(H2O)(2)][Co-2(phen)(2)(btc)(2)]}(n) 1 has been hydrothermally synthesized and characterized by elemental analyses, IR spectrum, TG analysis and single-crystal X-ray diffraction. Compound 1 crystallizes in the triclinic system, space group P (1) over bar, a = 7.7709(16) Angstrom, b = 10.572(2) Angstrom, c = 12.178(2) Angstrom, alpha = 88.49(3)degrees, beta = 77.97(3)degrees, gamma = 69.84(3)degrees, V = 917.5(3) Angstrom(3), Z = 1, R1 = 0.0571. The compound 1 exhibits a novel two-dimensional network with unusual (4,6)-lattice-type network constructed by [Co-2(phen)(2)(btc)(2)](2-) dimers and the [Co(H2O)(2)](2+), fragments. (C) 2003 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：728 / 732
页数：5
相关论文
共 50 条
  • [41] Synthesis and characterization of two isomers of two-dimensional networks compound [Cu(dafo)2(H2O)2] (ClO4)2
    Zhang, RL
    Zhao, JS
    Gu, AP
    He, SY
    [J]. ACTA CHIMICA SINICA, 2003, 61 (02) : 262 - 266
  • [42] Synthesis, structural characterisation and thermal decomposition of a new organic-inorganic hybrid material (C5H14N2)[Cu(SO4)2(H2O)4] • H2O
    Hajlaoui, Fadhel
    Yahyaoui, Samia
    Naili, Houcine
    Mhiri, Tahar
    Bataille, Thierry
    [J]. POLYHEDRON, 2009, 28 (11) : 2113 - 2118
  • [43] Crystal structures, spectral and magnetic properties of cobalt(II) pyridinecarboxylates: A novel polymeric chain in {[{2,6-(MeO)2nic}2(H2O)2Co(μ-H2O)Co(H2O)4(μ-H2O)]-{2,6-(MeO)2nic}2•6H2O}n
    Miklos, Dusan
    Jaskova, Jana
    Segl'a, Peter
    Korabik, Maria
    Mrozinski, Jerzy
    Sillanpaa, Reijo
    Mikuriya, Masahiro
    Melnik, Milan
    [J]. INORGANICA CHIMICA ACTA, 2006, 359 (13) : 4386 - 4392
  • [44] Hydrothermal Synthesis, Crystal Structure and Characterization of New Coordination Polymer [Co2(pydc)2(H2O)6]n·2nH2O
    Sumit Sanotra
    Rimpy Gupta
    Sonika Khajuria
    Haq Nawaz Sheikh
    Bansi Lal Kalsotra
    [J]. Journal of Inorganic and Organometallic Polymers and Materials, 2013, 23 : 897 - 906
  • [45] Hydrothermal Synthesis, Crystal Structure and Characterization of New Coordination Polymer [Co2(pydc)2(H2O)6] n •2nH2O
    Sanotra, Sumit
    Gupta, Rimpy
    Khajuria, Sonika
    Sheikh, Haq Nawaz
    Kalsotra, Bansi Lal
    [J]. JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, 2013, 23 (04) : 897 - 906
  • [46] Molecular recognition of an organic molecule through a two dimensional square network inclusion complex.: Synthesis and crystal structure of [Cd(4,4′-bpy)2(H2O)2] (BF4)2 • 2(4,4′-bpy) • (C6H6N2O2) • 2H2O
    Liu, CM
    Xiong, RG
    You, XZ
    Chen, W
    Lo, KM
    [J]. JOURNAL OF COORDINATION CHEMISTRY, 1998, 46 (02) : 211 - 220
  • [47] Synthesis and structure of a novel inorganic-organic hybrid framework microporous material Cd3(BDC)0.5(BTC)2(DMF) (H2O)•3DMF•H3O•H2O
    Shi, X
    Fang, QR
    Xin, MH
    Wu, G
    Tian, G
    Zhu, GS
    Li, YF
    Wang, LF
    Wang, CL
    Shang, TC
    Qiu, SL
    [J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2002, 23 (11): : 2040 - 2042
  • [48] Hydrothermal assembly and structural characterization of a novel 3D coordination polymer:: [Cd2Zn(BTC)2(H2O)4]n•2nH2O
    Chen, HX
    Liu, SX
    [J]. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2005, 24 (01) : 54 - 58
  • [49] Syntheses and crystal structures of two Cd(II) coordination polymers:: one-dimensional chain [Cd(C4H6N2)2(C4H2O4)(H2O)2]n and two-dimensional sheet [Cd(C4H6N2)(H2O)(C4H4O4)]n • nH2O
    Jin, Yi
    Che, Yunxia
    Zheng, Jimin
    [J]. JOURNAL OF COORDINATION CHEMISTRY, 2007, 60 (22-24) : 2679 - 2686
  • [50] A novel 3D organic-inorganic hybrid based on sandwich-type cadmium hetereopolymolybdate:: {[Cd4(H2O)2(2,2′-bpy)2] Cd[Mo6O12(OH)3(PO4)2(HPO4)2]2} [Mo2O4(2,2′-bpy)2]2•3H2O
    Guo, HX
    Liu, SX
    [J]. INORGANIC CHEMISTRY COMMUNICATIONS, 2004, 7 (11) : 1217 - 1220
12345