A novel two-dimensional organic-inorganic hybrid compound with a (4,6)-lattice-type network:: {[Co(H2O)2][Co2(phen)2(btc)2]}n(btc = benzene-1,2,4-tricarboxylate)

被引：9
作者：
Hao, N
Liu, FC
Wang, EB [1 ]
Huang, RD
Li, YG
Hu, CW
机构：
[1] NE Normal Univ, Dept Chem, Inst Polyoxometalate Chem, Changchun 130024, Jilin, Peoples R China
[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
[3] Beijing Inst Technol, Dept Chem, Sch Chem Engn & Mat, Beijing 100081, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2003年 / 6卷 / 06期
基金：
中国国家自然科学基金;
关键词：
coordination polymer; metal-organic network; hydrothermal synthesis; crystal structure;
D O I：
10.1016/S1387-7003(03)00094-7
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new organic-inorganic hybrid compound {[Co(H2O)(2)][Co-2(phen)(2)(btc)(2)]}(n) 1 has been hydrothermally synthesized and characterized by elemental analyses, IR spectrum, TG analysis and single-crystal X-ray diffraction. Compound 1 crystallizes in the triclinic system, space group P (1) over bar, a = 7.7709(16) Angstrom, b = 10.572(2) Angstrom, c = 12.178(2) Angstrom, alpha = 88.49(3)degrees, beta = 77.97(3)degrees, gamma = 69.84(3)degrees, V = 917.5(3) Angstrom(3), Z = 1, R1 = 0.0571. The compound 1 exhibits a novel two-dimensional network with unusual (4,6)-lattice-type network constructed by [Co-2(phen)(2)(btc)(2)](2-) dimers and the [Co(H2O)(2)](2+), fragments. (C) 2003 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：728 / 732
页数：5
相关论文
共 50 条
  • [31] Hydrothermal synthesis and characterization of a two-dimensional inorganic-organic hybrid gallophosphate (1,10-phen)Ga2(HPO4)2F2(H2O) with chiral layered structure
    Yang, YL
    Mu, ZC
    Wang, W
    Ye, L
    Chen, C
    Yi, Z
    Pang, WQ
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2004, 25 (05): : 793 - 796
  • [32] Synthesis and Characterization of Hybrid Organic-Inorganic, Dimeric Tungstoantimonate, {[Cu(En)2(H2O)]2[Cu4Na2(H2O)2(OH)2](α-SbW9O33)2}6-
    Li, J.
    Cheng, Y. M.
    Ma, P. T.
    Wang, J. P.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2012, 57 (06) : 827 - 831
  • [33] Synthesis and characterization of an organic-inorganic hybrid crystal: 2[Co(en)3](V4O13)•4H2O
    Vosegaard, Emilie Skytte
    Mamakhel, Mohammad Aref Hasen
    Parmar, Vijay Singh
    Bertelsen, Andreas Dueholm
    Iversen, Bo Brummerstedt
    ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS, 2024, 80 : 488 - 494
  • [34] A novel two-dimensional mixed molybdenum-vanadium polyoxometalate:: Synthesis, magnetic property and characterization Of [PMo8VIMo4VO40(VIVO)2{Co(phen)2}2](H3O)2[PMo4VIMo8VO40(VIVO)2{Co(phen)2(H2O)}2]
    Dai, Limei
    Ma, Ying
    Wang, Enbo
    Wang, Xinlong
    Lu, Ying
    Wang, Xiaolan
    JOURNAL OF MOLECULAR STRUCTURE, 2007, 829 (1-3) : 74 - 79
  • [35] Synthesis, crystal structure and properties of a new organic-inorganic hybrid Dawson-like polyoxotungstate [Co(2,2′-bpy)3]2[Co(2,2′-bpy)2Cl][Co(2,2′-bpy)2]H2[SbW18O60]·4H2O
    JingPing Wang
    PengTao Ma
    JingYang Niu
    Science in China Series B: Chemistry, 2007, 50 : 784 - 789
  • [36] Synthesis, crystal structure and properties of a new organic-inorganic hybrid Dawson-like polyoxotungstate [Co（2,2′-bpy）3]2[Co（2,2′-bpy）2Cl][Co（2,2′-bpy）2]H2- [SbW18O60]·4H2O
    WANG JingPing
    Science in China(Series B:Chemistry), 2007, (06) : 784 - 789
  • [37] Synthesis, crystal structure and properties of a new organic-inorganic hybrid Dawson-like polyoxotungstate [Co(2,2'-bpy)3]2[Co(2,2'-bpy)2Cl][Co(2,2'-bpy)2]H2-[SbW18O60]•4H2O
    Wang JingPing
    Ma PengTao
    Niu JingYang
    SCIENCE IN CHINA SERIES B-CHEMISTRY, 2007, 50 (06): : 784 - 789
  • [38] The Synthesis and Structural Characterization of Two-dimensional Coordination Polymer {[Ni(phen)H2O](μ4-C 10H2O8)1/2}n
    YE Ling 1
    ChemicalResearchinChineseUniversities, 2002, (04) : 474 - 477
  • [39] An inorganic-organic hybrid material {[Dy2(SO4)(Himdc)2(H2O)5]•H2O}n featuring organic carboxylic acid and inorganic sulfate and luminescent property
    Hailili, Reshalaiti
    Chang, Li-Xian
    Wang, Li
    Huang, Yi-Neng
    Qian, Wei
    Zeng, Ming-Hua
    Abulizi, Zulipiya
    INORGANIC CHEMISTRY COMMUNICATIONS, 2013, 35 : 113 - 116
  • [40] A novel maze-type network assembled by copper(II) and 2,2′-dicarboxydiphenylthioether:: [(Cu4(C5H5N)8{S(C6H4CO2)2}4(H2O)2]•2H2O)n
    Singh, RKB
    Malik, KMA
    Mahalli, SOG
    El Fallah, MS
    Karan, NK
    Mitra, S
    INORGANIC CHEMISTRY COMMUNICATIONS, 2001, 4 (06) : 315 - 318
12345