Pressure and temperature variation of the depolarized light scattering spectra of the fragile glass-former liquid salol

被引:8
|
作者
Pratesi, G
Bellosi, A
Barocchi, F
机构
[1] Ist Nazl Fis Mat, I-50125 Florence, Italy
[2] Univ Florence, I-50125 Florence, Italy
[3] Lab Europeo Spettroscopia Nonlineare, I-50125 Florence, Italy
来源
EUROPEAN PHYSICAL JOURNAL B | 2000年 / 18卷 / 02期
关键词
D O I
10.1007/PL00011072
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
The pressure and temperature dependences of the depolarized light scattering spectra of salol have been measured at isobaric condition P = 1 bar for T between 328 and 393 K, and at isothermal condition T = 343 K for P between 1 and 625 bar, i.e. outside the metastable liquid region. The experimental results for both the alpha- and beta -relaxations can be well described by the Mode Coupling Theory. The independence of the power-law parameters alpha, and consequently b and gamma, from the thermodynamic variables T and P is demonstrated. The critical temperature T-c at 1 bar and the critical pressure P-c at T = 343 K have been determined from the normal liquid state.
引用
收藏
页码:283 / 287
页数:5
相关论文
共 40 条