Constructing Robust Covalent Organic Frameworks via Multicomponent Reactions

被引：234

作者：

Wang, Peng-Lai ^{[1
]}

Ding, San-Yuan ^{[1
]}

Zhang, Zhi-Cong ^{[1
]}

Wang, Zhi-Peng ^{[1
]}

Wang, Wei ^{[1
]}

机构：

[1] Lanzhou Univ, Coll Chem & Chem Engn, State Key Lab Appl Organ Chem, Lanzhou 730000, Gansu, Peoples R China

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2019年 / 141卷 / 45期

基金：

中国国家自然科学基金;

关键词：

CARBON-DIOXIDE; CRYSTALLINE; STABILITY; EFFICIENT; HYDROGEN;

D O I：

10.1021/jacs.9b10625

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Methodology development of robust link-ages is fundamentally important for the synthesis and application of covalent organic frameworks (COFs). We report herein a new strategy based on multicomponent reactions (MCRs) to construct ultrastable COFs. With the one-pot formation of five covalent bonds in each cyclic joint, a series of imidazole-linked COFs were robustly constructed through the Debus-Radziszewski MCR from three easily available components. By reaching a higher level of complexity and precision in covalent assembly, this research explores a new direction in integrating sophisticated reversible/irreversible reactions to construct crystalline porous frameworks.

引用

页码：18004 / 18008

页数：5

共 62 条

[1] Vinylene-Linked Covalent Organic Frameworks by Base-Catalyzed Aldol Condensation [J].

Acharjya, Amitava ;

Pachfule, Pradip ;

Roeser, Jerome ;

Schmitt, Franz-Josef ;

Thomas, Arne .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2019, 58 (42) :14865-14870

[2]

[Anonymous], 2013, MAT STUD V 7 0

[3] Thiophene-based covalent organic frameworks [J].

Bertrand, Guillaume H. V. ;

Michaelis, Vladimir K. ;

Ong, Ta-Chung ;

Griffin, Robert G. ;

Dinca, Mircea .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2013, 110 (13) :4923-4928

[4] Covalent Organic Frameworks and Cage Compounds: Design and Applications of Polymeric and Discrete Organic Scaffolds [J].

Beuerle, Florian ;

Gole, Bappaditya .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2018, 57 (18) :4850-4878

[5] Extraction of Photogenerated Electrons and Holes from a Covalent Organic Framework Integrated Heterojunction [J].

Calik, Mona ;

Auras, Florian ;

Salonen, Laura M. ;

Bader, Kathrin ;

Grill, Irene ;

Handloser, Matthias ;

Medina, Dana D. ;

Dogru, Mirjam ;

Loebermann, Florian ;

Trauner, Dirk ;

Hartschuh, Achim ;

Bein, Thomas .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (51) :17802-17807

[6] Rationally synthesized two-dimensional polymers [J].

Colson, John W. ;

Dichtel, William R. .

NATURE CHEMISTRY, 2013, 5 (06) :453-465

[7] Porous, crystalline, covalent organic frameworks [J].

Côté, AP ;

Benin, AI ;

Ockwig, NW ;

O'Keeffe, M ;

Matzger, AJ ;

Yaghi, OM .

SCIENCE, 2005, 310 (5751) :1166-1170

[8] In-Depth Experimental and Computational Investigations for Remarkable Gas/Vapor Sorption, Selectivity, and Affinity by a Porous Nitrogen-Rich Covalent Organic Framework [J].

Das, Prasenjit ;

Mandal, Sanjay K. .

CHEMISTRY OF MATERIALS, 2019, 31 (05) :1584-1596

[9]

Debus H., 1858, ANN CHEM PHARM, V107, P199, DOI DOI 10.1002/JLAC.18581070209

[10] The atom, the molecule, and the covalent organic framework [J].

Diercks, Christian S. ;

Yaghi, Omar M. .

SCIENCE, 2017, 355 (6328)

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