Tridecanuclear CuII11Na2 Cagelike Silsesquioxanes

被引：23

作者：

Astakhov, Grigorii S. ^{[1
,2
]}

Bilyachenko, Alexey N. ^{[1
,2
]}

Levitsky, Mikhail M. ^{[1
]}

Korlyukov, Alexander A. ^{[2
,3
]}

Zubavichus, Yan, V ^{[4
]}

Dorovatovskii, Pavel, V ^{[4
]}

Khrustalev, Victor N. ^{[2
,4
]}

Vologzhanina, Anna V. ^{[1
]}

Shubina, Elena S. ^{[1
]}

机构：

[1] Russian Acad Sci, Nesmeyanov Inst Organoelement Cpds, Vavilov Str 28, Moscow 119991, Russia

[2] Peoples Friendship Univ Russia, Miklukho Maklay Str 6, Moscow 117198, Russia

[3] Pirogov Russian Natl Res Med Univ, Ostrovitianov Str 1, Moscow 117997, Russia

[4] Kurchatov Inst, Natl Res Ctr, Akad Kurchatova Pl 1, Moscow 123182, Russia

来源：

CRYSTAL GROWTH & DESIGN | 2018年 / 18卷 / 09期

关键词：

METAL-ORGANIC FRAMEWORKS; HIGH CATALYTIC-ACTIVITY; COORDINATION POLYMERS; MAGNETIC-PROPERTIES; OXIDATION; COPPER; COMPLEXES; LIGANDS; PERFORMANCE; SORPTION;

D O I：

10.1021/acs.cgd.8b00778

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of three unprecedented heterometallic copper(II) sodium silsesquioxanes were isolated (i) via the unusual rearrangement process during synthesis of coordination polymers or (ii) via the self-assembly reaction using 2,2'-bipyridine. The unique type of these products' molecular topology consists of an unusual fusion of two sandwich-like components (each including five copper and one sodium sites) via a central copper ion. These compounds correspond to the highest nuclearity among Cu(II)-based cage silsesquioxanes reported to date.

引用

页码：5377 / 5384

页数：8

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