Mixing Does the Magic: A Rapid Synthesis of High Surface Area Noble Metal Nanosponges Showing Broadband Nonlinear Optical Response

被引:116
作者
Krishna, Katla Sai [1 ]
Sandeep, C. S. Suchand [2 ]
Philip, Reji [2 ]
Eswaramoorthy, Muthusamy [1 ]
机构
[1] Jawaharlal Nehru Ctr Adv Sci Res, DST Unit Nanosci, Chem & Phys Mat Unit, Nanomat & Catalysis Lab, Bangalore 560064, Karnataka, India
[2] Raman Res Inst, Light & Matter Phys LAMP Grp, Bangalore 560080, Karnataka, India
关键词
nanosponges; porous nanostructures; noble metals; optical limiting; SERS; NANOWIRE NETWORKS; GOLD CATALYSTS; POROUS GOLD; SILVER; OXIDATION;
D O I
10.1021/nn100320s
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Here we report an instantaneous formation of high surface area metal nanosponges through a one-step inexpensive method in a completely green solvent, water. Merely by optimizing the concentration of the precursors and the reducing agent, we were able to generate a three-dimensional porous structure made up of nanowire networks. This is a general process, involves a simple, room temperature reduction of metal salts with sodium borohydride, and is therefore scalable to any amount. Further, these nanoporous metals because of their network structures show optical limiting behavior of a true broadband nature that would find applications in optoelectronic nanodevices.
引用
收藏
页码:2681 / 2688
页数:8
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