Thioester functional polymers

被引：75
作者：
Aksakal, Suzan [1 ]
Aksakal, Resat [1 ]
Becer, C. Remzi [1 ]
机构：
[1] Queen Mary Univ London, Sch Engn & Mat Sci, Polymer Chem Labs, Mile End Rd, London E1 4NS, England
来源：
POLYMER CHEMISTRY | 2018年 / 9卷 / 36期
基金：
欧盟地平线“2020”;
关键词：
RING-OPENING POLYMERIZATION; BUILDING-BLOCKS; EPSILON-THIOCAPROLACTONE; DIRECT POLYCONDENSATION; STAUDINGER LIGATION; CHAIN FLEXIBILITY; CARBOXYLIC-ACIDS; SOLVENT-FREE; SIDE-CHAIN; THIOL;
D O I：
10.1039/c8py00872h
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Inspired by the uniqueness and ubiquity of thioesters in nature, much attention has been paid to thioester functionalized materials, yielding applications ranging from responsive polymers to bioconjugates and (bio)degradable polymers. This review focuses on various applications of thioesters in polymer science, covering the synthesis and polymerisation of thioester containing monomers, thioester generation via polymerization processes or the presence of thioesters in chain ends, such as initiators or chain transfer agents. Examples of post-polymerization modifications with various compounds (e.g. thiols, azides, amines and cysteine containing peptides) to enable modification via pathways such as ligation, amidation or exchange reactions are also presented.
引用
收藏
页码：4507 / 4516
页数：11
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