Uptake of copper ions by carbon fiber/polymer hybrids prepared by tandem diazonium salt chemistry and in situ atom transfer radical polymerization

被引：42

作者：

Chergui, Samia Mahouche ^{[1
]}

Abbas, Nourredine ^{[1
]}

Matrab, Tarik ^{[2
,3
]}

Turmine, Mireille ^{[4
,5
]}

Nguyen, Elisabeth Bon ^{[6
,7
]}

Losno, Remi ^{[6
,7
]}

Pinson, Jean ^{[2
,3
]}

Chehimi, Mohamed M. ^{[1
]}

机构：

[1] Univ Paris Diderot, ITODYS, F-75013 Paris, France

[2] Ecole Super Phys & Chim Ind Ville Paris, LECA, F-75231 Paris 05, France

[3] CNRS, UMR7195, F-75231 Paris 05, France

[4] Univ Paris 06, LISE, F-75252 Paris 05, France

[5] CNRS, UPR 15, F-75252 Paris 05, France

[6] Univ Paris 12, Univ Paris Diderot, LISA, F-94010 Creteil, France

[7] CNRS, Fac Sci, F-94010 Creteil, France

来源：

CARBON | 2010年 / 48卷 / 07期

关键词：

HEAVY-METAL IONS; AQUEOUS-SOLUTION; ACTIVATED CARBONS; REMOVAL; ADSORPTION; FIBER; PRECONCENTRATION; REDUCTION; SURFACES; CATIONS;

D O I：

10.1016/j.carbon.2010.01.050

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Cyclam-functionalized polyglycidyl methacrylate, grafted on carbon fibres (CF-PGMA-Cy) was prepared by atom transfer radical polymerization using aryl diazonium salt initiators. These adsorption maximum capacity of CF-PGMA-Cy fibres for Cu(II) was found to be 28.6 mg/g at pH 5.2 and the adsorption kinetics fitted to the pseudo-second order model. Cyclic voltammetry of the (CF-PGMA-Cy)-supported copper ions indicated true electrochemical stripping of Cu(II) with detection of as low as 2 pmol of adsorbed Cu-0. CF-PGMA-Cy fibres are thus efficient and reusable adsorbents that hold promises for the design of electrochemical sensors of metal ions. (C) 2010 Elsevier Ltd. All rights reserved.

引用

页码：2106 / 2111

页数：6

共 30 条

[21] Modification of activated carbon using sodium acetate and its regeneration using sodium hydroxide for the adsorption of copper from aqueous solution
Mugisidi, Dan
Ranaldo, Aria
Soedarsono, Johny W.
Hikam, Muhammad
[J]. CARBON, 2007, 45 (05) : 1081 - 1084
[22] Attachment of organic layers to conductive or semiconductive surfaces by reduction of diazonium salts
Pinson, J
Podvorica, F
[J]. CHEMICAL SOCIETY REVIEWS, 2005, 34 (05) : 429 - 439
[23] Removal of copper from aqueous solution by aminated and protonated mesoporous aluminas: kinetics and equilibrium
Rengaraj, S
Kim, Y
Joo, CK
Yi, J
[J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2004, 273 (01) : 14 - 21
[24] Aminodiacetic water-soluble polymer-metal ion interactions
Rivas, Bernabe L.
Maureira, Antonio E.
Mondaca, Maria A.
[J]. EUROPEAN POLYMER JOURNAL, 2008, 44 (07) : 2330 - 2338
[25] Removal and enrichment of copper ions from aqueous solution by 1,8-diaminonapthalene polymer
Rutkowska, Joanna
Kilian, Krzysztof
Pyrzynska, Krystyna
[J]. EUROPEAN POLYMER JOURNAL, 2008, 44 (07) : 2108 - 2114
[26] Directly silica bonded analytical reagents: synthesis of 2-mercaptobenzothiazole-silica gel and its application as a new sorbent for preconcentration and determination of silver ion using solid-phase extraction method
Safavi, A
Iranpoor, N
Saghir, N
[J]. SEPARATION AND PURIFICATION TECHNOLOGY, 2004, 40 (03) : 303 - 308
[27] Biodegradable and thermoresponsive micelles of triblock copolymers based on 2-(N,N-dimethylamino)ethyl methacrylate and ε-caprolactone for controlled drug delivery
San Miguel, Veronica
Limer, A. J.
Haddleton, D. M.
Catalina, Fernando
Peinado, Carmen
[J]. EUROPEAN POLYMER JOURNAL, 2008, 44 (11) : 3853 - 3863
[28] Applications of pore-expanded mesoporous silica. 1. Removal of heavy metal cations and organic pollutants from wastewater
Sayari, A
Hamoudi, S
Yang, Y
[J]. CHEMISTRY OF MATERIALS, 2005, 17 (01) : 212 - 216
[29] Solid phase extractive preconcentration of trace metals using p-tert-butylcalix[4]arene-1,2-crown-4-anchored chloromethylated polymeric resin beads
Seyhan, Serap
Colak, Mehmet
Merdivan, Melek
Demirel, Nadir
[J]. ANALYTICA CHIMICA ACTA, 2007, 584 (02) : 462 - 468
[30] A Nafion-coated bismuth film electrode for the determination of heavy metals in vegetable using differential pulse anodic stripping voltammetry: An alternative to mercury-based electrodes
Xu, He
Zeng, Liping
Huang, Dekun
Man, Yuezhong
Jin, Litong
[J]. FOOD CHEMISTRY, 2008, 109 (04) : 834 - 839

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