Diffusion in glassy polymers

被引:19
作者
Vrentas, JS [1 ]
Vrentas, CM [1 ]
机构
[1] Penn State Univ, Dept Chem Engn, University Pk, PA 16802 USA
关键词
diffusion; glass transition; activation energy;
D O I
10.1002/polb.10433
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Two versions of the free-volume theory of diffusion are compared by considering differences in the predictions for the activation energy for the diffusion process. A number of data-theory comparisons for free-volume theory are discussed and evaluated. (C) 2003 Wiley Periodicals, Inc.
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页码:785 / 788
页数:4
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