Effective Enlargement of Fluorescence Resonance Energy Transfer of Poly-Porphyrin Mediated by β-Cyclodextrin Dimers

被引：67

作者：

Gu, Zhuo-Yi ^{[1
]}

Guo, Dong-Sheng ^{[1
]}

Sun, Mo ^{[1
]}

Liu, Yu ^{[1
]}

机构：

[1] Nankai Univ, Dept Chem, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2010年 / 75卷 / 11期

关键词：

LIGHT-HARVESTING DENDRIMERS; ATOMIC-FORCE MICROSCOPY; MULTIPORPHYRIN ARRAYS; PHOTOPHYSICAL PROPERTIES; PHOTOINDUCED ELECTRON; INCLUSION COMPLEXES; TRANSFER CASSETTES; BORON-DIPYRRIN; AQUEOUS-MEDIA; BODIPY DYES;

D O I：

10.1021/jo100351f

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

4,4-Difluoro-4-bora-3a,4a-diaza-s-indacene bridged bis(permethyl-beta-cyclodextrins) I was synthesized successfully through click chemistry, and it forms a well-defined linear assembly with 5,10,15,20-tetrakis(4-sulfonatophenyl)porphyrin 2 via extremely strong host-guest interactions, which was identified by the met hods of UV-vis, NMR, AFM, and TEM, respectively. Furthermore, the fluorescence resonance energy transfer from host spacer to porphyrin guest was investigated, showing that the energy transfer quantum yield is high to 94% in virtue of such a noncovalent path.

引用

页码：3600 / 3607

页数：8

共 53 条

[1] Water-soluble through-bond energy transfer cassettes for intracellular imaging [J].

Bandichhor, Rakeshwar ;

Petrescu, Anca D. ;

Vespa, Aude ;

Kier, Ann B. ;

Schroeder, Friedhelm ;

Burgess, Kevin .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (33) :10688-10689

[2] BODIPY-based hydroxyaryl derivatives as fluorescent pH probes [J].

Baruah, M ;

Qin, WW ;

Basaric, N ;

De Borggraeve, WM ;

Boens, N .

JOURNAL OF ORGANIC CHEMISTRY, 2005, 70 (10) :4152-4157

[3] TOPOGRAPHY OF CYCLODEXTRIN INCLUSION COMPLEXES .20. CIRCULAR AND FLIP-FLOP HYDROGEN-BONDING IN BETA-CYCLODEXTRIN UNDECAHYDRATE - A NEUTRON-DIFFRACTION STUDY [J].

BETZEL, C ;

SAENGER, W ;

HINGERTY, BE ;

BROWN, GM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (24) :7545-7557

[4] Fullerene-porphyrin constructs [J].

Boyd, PDW ;

Reed, CA .

ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (04) :235-242

[5] Bioinspired molecular design of light-harvesting multiporphyrin arrays [J].

Choi, MS ;

Yamazaki, T ;

Yamazaki, I ;

Aida, T .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (02) :150-158

[6] Energy transfer followed by electron transfer in a supramolecular triad composed of boron dipyrrin, zinc porphyrin, and fullerene: A model for the photosynthetic antenna-reaction center complex [J].

D'Souza, F ;

Smith, PM ;

Zandler, ME ;

McCarty, AL ;

Itou, M ;

Araki, Y ;

Ito, O .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (25) :7898-7907

[7] Competitive photoinduced electron transfer by the complex formation of porphyrin with cyclodextrin bearing viologen [J].

Deng, Wei ;

Onji, Takeshi ;

Yamaguchi, Hiroyasu ;

Ikeda, Noriaki ;

Harada, Akira .

CHEMICAL COMMUNICATIONS, 2006, (40) :4212-4214

[8] Ultrafast guest dynamics in cyclodextrin nanocavities [J].

Douhal, A .

CHEMICAL REVIEWS, 2004, 104 (04) :1955-1976

[9]

FABRICIO AL, 2005, ENERG FUEL, V19, P477

[10] Development of bioinspired artificial photosynthetic systems [J].

Fukuzumi, Shunichi .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2008, 10 (17) :2283-2297

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