Determination of texture by infrared spectroscopy in titanium oxide-anatase thin films

被引:52
作者
Pecharromán, C
Gracía, F
Holgado, JP
Ocaña, M
González-Elipe, AR
Bassas, J
Santiso, J
Figueras, A
机构
[1] CSIC, Inst Ciencia Mat, E-28049 Madrid, Spain
[2] Univ Seville, CSIC, Inst Ciencia Mat, Seville 41092, Spain
[3] Serv Cientificotecn UB, Barcelona 08028, Spain
[4] CSIC, Inst Ciencia Mat Barcelona, Bellaterra 08193, Spain
关键词
D O I
10.1063/1.1560858
中图分类号
O59 [应用物理学];
学科分类号
摘要
A theoretical model to determine the effective dielectric tensor of heterogeneous materials composed by anisotropic microcrystallites has been introduced to explain the infrared spectral features of textured thin films of uniaxial materials as the function of a textural parameter. This theoretical treatment is able to satisfactorily reproduce the experimental absorbance spectra of TiO2-anatase thin films chosen as a model system. Comparison of texture data obtained from infrared spectroscopy and x-ray diffraction are in good agreement which support the validity of the proposed model. (C) 2003 American Institute of Physics.
引用
收藏
页码:4634 / 4645
页数:12
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