Dependence of the protonation constants of organic compounds on their molecular volume

被引：5

作者：

Zevatskii, Yu. E. ^{[1
]}

Vlasov, E. A. ^{[1
]}

机构：

[1] St Petersburg State Inst Technol, St Petersburg 190013, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2007年 / 77卷 / 02期

关键词：

D O I：

10.1134/S1070363207020089

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An approach has been developed, which establishes a linear correlation between molecular parameters of organic compounds with account taken of atomic contributions. Relations between the energy of protonation of 395 organic compounds divided into four groups and their molecular volume were drawn. The differences between the experimental and calculated values within each group did not exceed 4%.

引用

页码：234 / 240

页数：7

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