Synthesis and crystal structure of one dimensional chain manganese complex [Mn2(C7H4O3)4(CH3OH)2]•4H2O•2CH3OH

被引：0

作者：

Li, JA ^{[1
]}

Zhang, FX

Wu, AZ

Shi, QZ

Li, YZ

Wang, LF

机构：

[1] NW Univ Xian, Shanxi Key Lab Phosicoinorgan Chem, Xian 710069, Peoples R China

[2] Lanzhou Univ, Dept Chem, Lanzhou 730000, Peoples R China

来源：

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2003年 / 22卷 / 01期

关键词：

one dimensional chain manganese (IV) complex; crystal structure; synthesis;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The one dimensional chain manganese complex [Mn-2(C7H4O3)(4)(CH3OH)(2)].4H(2)O.2CH(3)OH has been synthesized, and it was characterized by IR, X-ray diffraction and UV-Vis. X-ray diffraction result shows that the crystal belongs to triclinic, space group P (1) over bar with a = 7.653(5), b = 10.486(7), c = 12.943(8) Angstrom, alpha = 103.24(1), beta = 104.55(1), gamma = 110.11(1)degrees, V = 885.4(9) Angstrom(3) and Z = 1. UV-Vis spectrum result indicates there exists a peak at 547 nm, corresponding to the electron transition of d-d.

引用

页码：93 / 96

页数：4

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