A Highly Sensitive Carbendazim Sensor Based on Electrochemically Reduced Graphene Oxide

被引：9
作者：
Dong, Xiao-Ya [1 ]
Qiu, Bai-Jing [1 ]
Yang, Xing-Wang [1 ]
Jiang, Ding [1 ]
Wang, Kun [1 ]
机构：
[1] Jiangsu Univ, Inst Agr Engn, Key Lab Modern Agr Equipment & Technol MOE, Zhenjiang 212013, Jiangsu, Peoples R China
来源：
ELECTROCHEMISTRY | 2014年 / 82卷 / 12期
基金：
中国博士后科学基金; 中国国家自然科学基金;
关键词：
Electrochemically Reduced Graphene Oxide; Carbendazim; Differential Pulse Voltammetry; Electrochemical Sensor; PERFORMANCE LIQUID-CHROMATOGRAPHY; MODIFIED ELECTRODE; CAPILLARY-ELECTROPHORESIS; FUNGICIDE CARBENDAZIM; PESTICIDES; MICROEXTRACTION; THIABENDAZOLE; NANOPARTICLES; POLLUTANTS; DOPAMINE;
D O I：
10.5796/electrochemistry.82.1061
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
A simple method for direct and quantitative determination of carbendazim using electrochemically reduced graphene oxide modified glassy carbon electrode (ERGO/GCE) has been developed. The obtained electrode was characterized using scanning electron microscopy, Raman spectroscopy, cyclic voltammetry and differential pulse voltammetry. Compared to bare and graphene oxide modified electrodes (GO/GCE), the ERGO/GCE not only significantly shifted to a lower positive potential, but also noticeably enhanced the current response. The resulting carbendazim sensor showed a wide linear range (2.0 nM to 400 nM) and a low detection limit (1.0 nM). In addition, the proposed sensor has excellent selectivity, good stability and can be successfully applied in soil sample. The ERGO, which was obtained by facile, cost-effective method, could provide a promising platform to develop excellent electrochemical sensors for detecting carbendazim. (C) The Electrochemical Society of Japan, All rights reserved.
引用
收藏
页码：1061 / 1066
页数：6
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