Hollow nickel-aluminium-manganese layered triple hydroxide nanospheres with tunable architecture for supercapacitor application

被引:22
作者
Chandrasekaran, Nivedhini Iswarya [1 ]
Muthukumar, Harshiny [1 ]
Sekar, Aiswarya Devi [1 ]
Manickam, Matheswaran [1 ]
机构
[1] Natl Inst Technol, Dept Chem Engn, Tiruchirappalli 620015, Tamil Nadu, India
关键词
Hollow shell; Triple layered hydroxide; Supercapacitor; Ni-Al-Mn hydroxide; Nanocomposite; Tunable architecture; ELECTRODE MATERIALS; COMPOSITE ELECTRODES; ENERGY DENSITY; HIGH-POWER; PERFORMANCE; MICROSPHERES; SPHERES; NANOSHEETS; INTERFACE; NANOTUBES;
D O I
10.1016/j.matchemphys.2017.04.027
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Hollow triple layered Ni-Al-Mn hydroxide nanocomposite is a promising electrode material with high capacitance value. Moreover, the material provides a high energy density with good cycling stability. Here we demonstrate the facile method for preparation of hollow layered triple hydroxide material in a combination of Nickel, Aluminium and Manganese with high surface area and mesoporous nature. Owing to its high electrode area and fast electron-ion transfer nature, the hollow Ni-Al-Mn hydroxide exhibits the high capacitance of 1756 F/g at 4 A/g and retains its capacitance value upto 89.5% of initial values after 4000 cycles. Additionally, it provides a higher energy density of 239.0795 Wh/kg at a power density of 1980 W/kg. HLTH of Ni-Al-Mn nanocomposite provides a better capacitance effect. Finally, this material provides a general approach for designing supercapacitor with tunable nanostructure and enhanced supercapacitor behaviour has a large application in energy storage and conversion devices. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码:247 / 258
页数:12
相关论文
共 58 条
[1]   Synthesis and characterization by FTIR spectroscopy of silica aerogels prepared using several Si(OR)4 and R"Si(OR′)3 precursors [J].
Al-Oweini, Rami ;
El-Rassy, Houssam .
JOURNAL OF MOLECULAR STRUCTURE, 2009, 919 (1-3) :140-145
[2]   Electrodeposited polyethylenedioxythiophene with infiltrated gel electrolyte interface: a close contest of an all-solid-state supercapacitor with its liquid-state counterpart [J].
Anothumakkool, Bihag ;
Torris, Arun A. T. ;
Bhange, Siddheshwar N. ;
Badiger, Manohar V. ;
Kurungot, Sreekumar .
NANOSCALE, 2014, 6 (11) :5944-5952
[3]   R&D considerations for the performance and application of electrochemical capacitors [J].
Burke, Andrew .
ELECTROCHIMICA ACTA, 2007, 53 (03) :1083-1091
[4]   Synthesis of hierarchical porous NiO nanotube arrays for supercapacitor application [J].
Cao, F. ;
Pan, G. X. ;
Xia, X. H. ;
Tang, P. S. ;
Chen, H. F. .
JOURNAL OF POWER SOURCES, 2014, 264 :161-167
[5]   Nickel- Cobalt Layered Double Hydroxide Nanosheets for High- performance Supercapacitor Electrode Materials [J].
Chen, Hao ;
Hu, Linfeng ;
Chen, Min ;
Yan, Yan ;
Wu, Limin .
ADVANCED FUNCTIONAL MATERIALS, 2014, 24 (07) :934-942
[6]  
Deshpande R.P, 2014, ULTRACAPACITORS FUTU
[7]   Activated carbon nanospheres derived from bio-waste materials for supercapacitor applications - a review [J].
Divyashree, A. ;
Hegde, Gurumurthy .
RSC ADVANCES, 2015, 5 (107) :88339-88352
[8]   Microwave-assisted synthesis of metal oxide/hydroxide composite electrodes for high power supercapacitors - A review [J].
Faraji, Soheila ;
Ani, Farid Nasir .
JOURNAL OF POWER SOURCES, 2014, 263 :338-360
[9]  
Feng Ju, 2014, 2014 IEEE International Conference on Automation Science and Engineering (CASE), P143, DOI 10.1109/CoASE.2014.6899318
[10]   Shape-engineerable and highly densely packed single-walled carbon nanotubes and their application as super-capacitor electrodes [J].
Futaba, Don N. ;
Hata, Kenji ;
Yamada, Takeo ;
Hiraoka, Tatsuki ;
Hayamizu, Yuhei ;
Kakudate, Yozo ;
Tanaike, Osamu ;
Hatori, Hiroaki ;
Yumura, Motoo ;
Iijima, Sumio .
NATURE MATERIALS, 2006, 5 (12) :987-994