Solvothermal synthesis of novel antimony sulphides containing [Sb4S7]2- units

被引：44
|
作者：
Vaqueiro, P [1 ]
Darlow, DP
Powell, AV
Chippindale, AM
机构：
[1] Heriot Watt Univ, Dept Chem, Edinburgh EH14 4AS, Midlothian, Scotland
[2] Univ Reading, Sch Chem, Reading RG6 6AD, Berks, England
来源：
SOLID STATE IONICS | 2004年 / 172卷 / 1-4期
关键词：
solvothermal synthesis; antimony sulphide; crystal structure;
D O I：
10.1016/j.ssi.2004.01.064
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Two new antimony sulphides have been prepared solvothermally and characterised by single-crystal X-ray diffraction. [Co(en)(3)][Sb4S7] (1) was prepared at 140 degreesC from COS, Sb2S3 and S in the presence of ethylenediamine, whilst heating a mixture of Sb2S3, Co and S in tris(2aminoethyl)amine, N(CH2CH2NH2)(3), at 180 degreesC fegults in the formation of [C6H20N4][Sb4S7] (2). Both materials contain [Sb4S7](2-) chains formed from linkage of cyclic Sb3S63- units by SbS33- pyramids. In (1), the [Sb4S7] chains are linked by secondary Sb-S interactions to form sheets, between which the. charge balancing [Co(en)(3)](2+) cations reside. The structure of (2) involves interconnection of pairs of [Sb4S7](2-) chains through Sb2S2 rings to form isolated [Sb4S7](2-) double chains which are interleaved by protonated template molecules. (C) 2004 Elsevier B.V. All rights resereved.
引用
收藏
页码：601 / 605
页数：5
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