Unusual regioselectivity in Pd(0)-catalyzed coupling of allylic monoacetates and nitroalkanes: one-pot isomerization-alkylation

被引：1

作者：

Khan, Pasha M. ^{[1
]}

Bisht, Kirpal S. ^{[1
]}

机构：

[1] Univ S Florida, Dept Chem, Tampa, FL 33620 USA

来源：

TETRAHEDRON LETTERS | 2010年 / 51卷 / 10期

关键词：

(PI-ALLYL)PALLADIUM COMPLEXES; CATALYZED REACTION; ALLYLATION; NITRO; SUBSTITUTIONS; CONVERSION; MECHANISM; ATTACK;

D O I：

10.1016/j.tetlet.2010.01.025

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A hitherto unknown palladium-catalyzed reaction of nitroalkanes with hydroxy allylic acetates is reported. The reaction led to the formation of gamma-nitrocarbonyl Compounds instead of the usual unsaturated nitroalcohol expected upon displacement of the allylic acetate group. (C) 2010 Elsevier Ltd. All rights reserved.

引用

页码：1407 / 1410

页数：4

共 48 条

[1] PALLADIUM CATALYZED C-ALLYLATION OF NITROALKANES [J].