Turn-On Luminescence Sensing and Real-Time Detection of Traces of Water in Organic Solvents by a Flexible Metal-Organic Framework

被引：318

作者：

Douvali, Antigoni ^{[1
]}

Tsipis, Athanassios C. ^{[1
]}

Eliseeva, Svetlana V. ^{[2
]}

Petoud, Stephane ^{[2
]}

Papaefstathiou, Giannis S. ^{[3
]}

Malliakas, Christos D. ^{[4
]}

Papadas, Ioannis ^{[5
]}

Armatas, Gerasimos S. ^{[5
]}

Margiolaki, Irene ^{[6
]}

Kanatzidis, Mercouri G. ^{[4
]}

Lazarides, Theodore ^{[7
]}

Manos, Manolis J. ^{[1
]}

机构：

[1] Univ Ioannina, Dept Chem, GR-45110 Ioannina, Greece

[2] CNRS, Ctr Biophys Mol, UPR 4301, Orleans, France

[3] Univ Athens, Dept Chem, Zografos 15771, Greece

[4] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA

[5] Univ Crete, Dept Mat Sci & Technol, Iraklion 71003, Greece

[6] Univ Patras, Dept Biol, Patras 26500, Greece

[7] Aristotle Univ Thessaloniki, Dept Chem, Thessaloniki 54124, Greece

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2015年 / 54卷 / 05期

基金：

美国国家科学基金会;

关键词：

crystal engineering; luminescence; metal-organic frameworks; microporous materials; sensors; PHOTOLUMINESCENCE; HUMIDITY; SOLIDS;

D O I：

10.1002/anie.201410612

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The development of efficient sensors for the determination of the water content in organic solvents is highly desirable for a number of chemical industries. Presented herein is a Mg2+ metal-organic framework (MOF), which exhibits the remarkable capability to rapidly detect traces of water (0.05-5% v/v) in various organic solvents through an unusual turn-on luminescence sensing mechanism. The extraordinary sensitivity and fast response of this MOF for water, and its reusability make it one of the most powerful water sensors known.

引用

页码：1651 / 1656

页数：6

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