Turn-On Luminescence Sensing and Real-Time Detection of Traces of Water in Organic Solvents by a Flexible Metal-Organic Framework

被引：307
|
作者：
Douvali, Antigoni [1 ]
Tsipis, Athanassios C. [1 ]
Eliseeva, Svetlana V. [2 ]
Petoud, Stephane [2 ]
Papaefstathiou, Giannis S. [3 ]
Malliakas, Christos D. [4 ]
Papadas, Ioannis [5 ]
Armatas, Gerasimos S. [5 ]
Margiolaki, Irene [6 ]
Kanatzidis, Mercouri G. [4 ]
Lazarides, Theodore [7 ]
Manos, Manolis J. [1 ]
机构：
[1] Univ Ioannina, Dept Chem, GR-45110 Ioannina, Greece
[2] CNRS, Ctr Biophys Mol, UPR 4301, Orleans, France
[3] Univ Athens, Dept Chem, Zografos 15771, Greece
[4] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA
[5] Univ Crete, Dept Mat Sci & Technol, Iraklion 71003, Greece
[6] Univ Patras, Dept Biol, Patras 26500, Greece
[7] Aristotle Univ Thessaloniki, Dept Chem, Thessaloniki 54124, Greece
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2015年 / 54卷 / 05期
基金：
美国国家科学基金会;
关键词：
crystal engineering; luminescence; metal-organic frameworks; microporous materials; sensors; PHOTOLUMINESCENCE; HUMIDITY; SOLIDS;
D O I：
10.1002/anie.201410612
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The development of efficient sensors for the determination of the water content in organic solvents is highly desirable for a number of chemical industries. Presented herein is a Mg2+ metal-organic framework (MOF), which exhibits the remarkable capability to rapidly detect traces of water (0.05-5% v/v) in various organic solvents through an unusual turn-on luminescence sensing mechanism. The extraordinary sensitivity and fast response of this MOF for water, and its reusability make it one of the most powerful water sensors known.
引用
收藏
页码：1651 / 1656
页数：6
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