Turn-On Luminescence Sensing and Real-Time Detection of Traces of Water in Organic Solvents by a Flexible Metal-Organic Framework

被引：307

作者：

Douvali, Antigoni ^{[1
]}

Tsipis, Athanassios C. ^{[1
]}

Eliseeva, Svetlana V. ^{[2
]}

Petoud, Stephane ^{[2
]}

Papaefstathiou, Giannis S. ^{[3
]}

Malliakas, Christos D. ^{[4
]}

Papadas, Ioannis ^{[5
]}

Armatas, Gerasimos S. ^{[5
]}

Margiolaki, Irene ^{[6
]}

Kanatzidis, Mercouri G. ^{[4
]}

Lazarides, Theodore ^{[7
]}

Manos, Manolis J. ^{[1
]}

机构：

[1] Univ Ioannina, Dept Chem, GR-45110 Ioannina, Greece

[2] CNRS, Ctr Biophys Mol, UPR 4301, Orleans, France

[3] Univ Athens, Dept Chem, Zografos 15771, Greece

[4] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA

[5] Univ Crete, Dept Mat Sci & Technol, Iraklion 71003, Greece

[6] Univ Patras, Dept Biol, Patras 26500, Greece

[7] Aristotle Univ Thessaloniki, Dept Chem, Thessaloniki 54124, Greece

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2015年 / 54卷 / 05期

基金：

美国国家科学基金会;

关键词：

crystal engineering; luminescence; metal-organic frameworks; microporous materials; sensors; PHOTOLUMINESCENCE; HUMIDITY; SOLIDS;

D O I：

10.1002/anie.201410612

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The development of efficient sensors for the determination of the water content in organic solvents is highly desirable for a number of chemical industries. Presented herein is a Mg2+ metal-organic framework (MOF), which exhibits the remarkable capability to rapidly detect traces of water (0.05-5% v/v) in various organic solvents through an unusual turn-on luminescence sensing mechanism. The extraordinary sensitivity and fast response of this MOF for water, and its reusability make it one of the most powerful water sensors known.

引用

页码：1651 / 1656

页数：6

共 33 条

[1] [Anonymous], ANGEW CHEM, DOI DOI 10.1002/(ISSN)1521-3757
[2] Applied Topological Analysis of Crystal Structures with the Program Package ToposPro
Blatov, Vladislav A.
Shevchenko, Alexander P.
Proserpio, Davide M.
[J]. CRYSTAL GROWTH & DESIGN, 2014, 14 (07) : 3576 - 3586
[3] A Luminescent Metal-Organic Framework with Lewis Basic Pyridyl Sites for the Sensing of Metal Ions
Chen, Banglin
Wang, Liangbo
Xiao, Yunqing
Fronczek, Frank R.
Xue, Ming
Cui, Yuanjing
Qian, Guodong
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (03) : 500 - 503
[4] A Highly Selective Pyrophosphate Sensor Based on ESIPT Turn-On in Water
Chen, Wei-Hua
Xing, Yu
Pang, Yi
[J]. ORGANIC LETTERS, 2011, 13 (06) : 1362 - 1365
[5] Highly sensitive fluorescent sensing for water based on poly(m-aminobenzoic acid)
Deng, Qiliang
Li, Yanli
Wu, Jianhua
Liu, Yang
Fang, Guozhen
Wang, Shuo
Zhang, Yukui
[J]. CHEMICAL COMMUNICATIONS, 2012, 48 (24) : 3009 - 3011
[6] Lanthanide luminescence for functional materials and bio-sciences
Eliseeva, Svetlana V.
Buenzli, Jean-Claude G.
[J]. CHEMICAL SOCIETY REVIEWS, 2010, 39 (01) : 189 - 227
[7] Hybrid porous solids:: past, present, future
Ferey, Gerard
[J]. CHEMICAL SOCIETY REVIEWS, 2008, 37 (01) : 191 - 214
[8] Metal-organic nanoporous structures with anisotropic photoluminescence and magnetic properties and their use as sensors
Harbuzaru, Bogdan V.
Corma, Avelino
Rey, Fernando
Atienzar, Pedro
Jorda, Jose L.
Garcia, Hermenegildo
Ananias, Duarte
Carlos, Luis D.
Rocha, Joao
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (06) : 1080 - 1083
[9] Horike S, 2009, NAT CHEM, V1, P695, DOI [10.1038/NCHEM.444, 10.1038/nchem.444]
[10] Recent Experimental Advances on Excited-State Intramolecular Proton Coupled Electron Transfer Reaction
Hsieh, Cheng-Chih
Jiang, Chang-Ming
Chou, Pi-Tai
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 2010, 43 (10) : 1364 - 1374

← 1 2 3 4 →