Peroxidase-like Activity of Metal-Organic Framework [Cu(PDA)(DMF)] and Its Application for Colorimetric Detection of Dopamine

被引:139
|
作者
Wang, Jun [1 ]
Hu, Yuyan [1 ]
Zhou, Qi [1 ]
Hu, Lianzhe [1 ]
Fu, Wensheng [1 ]
Wang, Yi [1 ]
机构
[1] Chongqing Normal Univ, Coll Chem, Chongqing Key Lab Green Synth & Applicat, Chongqing 401331, Peoples R China
基金
中国国家自然科学基金;
关键词
metal-organic frameworks; peroxidase; nanozyme; copper; dopamine; GLUCOSE; ENZYMES; NANOPARTICLES; DNA;
D O I
10.1021/acsami.9b17488
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
A metal-organic framework (MOF) [Cu(PDA)(DMF)] was synthesized under mild mixed solvothermal conditions. It is constructed by 1,10-phenanthroline-2,9-dicarboxylic acid (H(2)PDA) and Cu2+ ions. The complex exhibits high peroxidase-like activity and can catalytically oxidize the colorless substrate 3,3',5,5'-tetramethylbenzidine to a blue product in the presence of H2O2. However, the peroxidase-like activity of [Cu(PDA)(DMF)] can be potently inhibited in the presence of dopamine. Based on this phenomenon, the colorimetric detection of dopamine was demonstrated with good selectivity and high sensitivity. [Cu(PDA)(DMF)] showed good stability and robust catalytic activity, which has been employed in the detection of dopamine in human urine and pharmaceutical samples.
引用
收藏
页码:44466 / 44473
页数:8
相关论文
共 50 条
  • [21] Histidine-engineered metal-organic frameworks with enhanced peroxidase-like activity for sensitive detection of metallothioneins
    Sha, Meng
    Xu, Weiqing
    Wu, Yu
    Jiao, Lei
    Chen, Yifeng
    Huang, Jiajia
    Tang, Yinjun
    Gu, Wenling
    Zhu, Chengzhou
    SENSORS AND ACTUATORS B-CHEMICAL, 2022, 366
  • [22] Facile colorimetric detection of As(V) in Rice with immobilized acid phosphatase on hollow metal-organic frameworks hybrid with peroxidase-like activity
    Qin, Zhiyang
    Xu, Zhuolan
    Liu, Yixin
    Qin, Xinguang
    Liu, Gang
    Wei, Xinlin
    Zhang, Haizhi
    FOOD CHEMISTRY-X, 2025, 25
  • [23] Vanadium-Based Metal-Organic Frameworks with Peroxidase-like Activity as a Colorimetric Sensing Platform for Direct Detection of Organophosphorus Pesticides
    Du, Ningjing
    Weng, Wenchuan
    Xu, Yuanyuan
    Zhou, Yi
    Yi, Yinhui
    Zhao, Yong
    Zhu, Gangbing
    INORGANIC CHEMISTRY, 2024, 63 (35) : 16442 - 16450
  • [24] PVP-stabilized PtRu nanozymes with peroxidase-like activity and its application for colorimetric and fluorometric glucose detection
    Park, Yosep
    Gupta, Pramod K.
    Tran, Van-Khue
    Son, Seong Eun
    Hur, Won
    Lee, Han Been
    Park, Ji Yeon
    Kim, Seong Nyeon
    Seong, Gi Hun
    COLLOIDS AND SURFACES B-BIOINTERFACES, 2021, 204
  • [25] Metal-organic framework coated Fe3O4 magnetic nanoparticles with peroxidase-like activity for colorimetric sensing of cholesterol
    Wu, Yanzi
    Ma, Yujie
    Xu, Guanhong
    Wei, Fangdi
    Ma, Yunsu
    Song, Quan
    Wang, Xu
    Tang, Tang
    Song, Yueyue
    Shi, Menglan
    Xu, Xiaoman
    Hu, Qin
    SENSORS AND ACTUATORS B-CHEMICAL, 2017, 249 : 195 - 202
  • [26] Peroxidase-Like Platinum Clusters Synthesized by Ganoderma lucidum Polysaccharide for Sensitively Colorimetric Detection of Dopamine
    Lai, Xiang
    Han, Yu
    Zhang, Jie
    Zhang, Jinyu
    Lin, Weifeng
    Liu, Zhiwei
    Wang, Longgang
    MOLECULES, 2021, 26 (09):
  • [27] Ultrasmall Au nanoparticles modified 2D metalloporphyrinic metal-organic framework nanosheets with high peroxidase-like activity for colorimetric detection of organophosphorus pesticides
    Yang, Huanyu
    Sun, Zhiping
    Qin, Xinguang
    Wu, Hongyuan
    Zhang, Haizhi
    Liu, Gang
    FOOD CHEMISTRY, 2022, 376
  • [28] Water-stable metal-organic frameworks with intrinsic peroxidase-like catalytic activity as a colorimetric biosensing platform
    Zhang, Jian-Wei
    Zhang, Hao-Tian
    Du, Zi-Yi
    Wang, Xueqing
    Yu, Shu-Hong
    Jiang, Hai-Long
    CHEMICAL COMMUNICATIONS, 2014, 50 (09) : 1092 - 1094
  • [29] Peroxidase-like activity of vanadium tetrasulfide submicrospheres and its application to the colorimetric detection of hydrogen peroxide and L-cysteine
    Chen, Chao
    Wang, Yi
    Zhang, Dun
    MICROCHIMICA ACTA, 2019, 186 (12)
  • [30] Colorimetric Sensing of Dopamine Based on Peroxidase-Like Activity of Gold Nanoparticles
    Shaoping Cuifeng Jiang
    Juhua Pang
    Xueran Luo
    Wei Liu
    Wanquan Guo
    Journal of Analytical Chemistry, 2019, 74 : 679 - 685