Nonlinear Optical Properties of Polyynes: An Experimental Prediction for Carbyne

被引：31

作者：

Agarwal, Nisha R. ^{[1
,5
]}

Lucotti, Andrea ^{[1
]}

Tommasini, Matteo ^{[1
]}

Chalifoux, Wesley A. ^{[2
]}

Tykwinski, Rik R. ^{[3
,4
]}

机构：

[1] Politecn Milan, Dipartimento Chim Mat & Ingn Chim Giulio Natta, Piazza Leonardo da Vinci 32, I-20133 Milan, Italy

[2] Univ Nevada, Dept Chem, Reno, NV 89557 USA

[3] Univ Erlangen Nurnberg, Dept Chem & Pharm, Henkestr 42, D-91054 Erlangen, Germany

[4] Univ Erlangen Nurnberg, ICMM, Henkestr 42, D-91054 Erlangen, Germany

[5] Chalmers Univ Technol, S-41296 Gothenburg, Sweden

来源：

JOURNAL OF PHYSICAL CHEMISTRY C | 2016年 / 120卷 / 20期

基金：

加拿大自然科学与工程研究理事会;

关键词：

EFFECTIVE CONJUGATION LENGTH; RAMAN-SPECTROSCOPY; CARBON CHAINS; ORGANIC MATERIALS; CAPPED POLYYNES; LASER-ABLATION; HYPERPOLARIZABILITY; MOLECULES; OLIGOMERS; MODEL;

D O I：

10.1021/acs.jpcc.6b03071

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We present the experimental determination of the vibrational contribution to molecular second hyperpolarizability (gamma(vib)) of very long polyynes that have been recently made available thanks to progress in chemical synthesis. Based on a simple theoretical model, the available experimental data allow estimating the asymptotic behavior of the vibrational contribution to molecular hyperpolarizability for increasing chain length.

引用

页码：11131 / 11139

页数：9

共 50 条

[21] Nonlinear optical properties of diazabutadienes and -hexatrienes; experimental and computational aspects
Dworczak, R
Fabian, WMF
Reidlinger, C
Rumpler, A
Schachner, J
Zangger, K
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2002, 58 (10) : 2135 - 2144
[22] Exploring the antibacterial properties of polyynes
Uthappa, Diya
Young, Douglas
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2017, 254
[23] Hyperbranched Organometallic Polyynes:Optical and Thermal Properties and Their Transformation into Soft Ferromagnetic Ceramics
M. Huβler
J. W. Y. Lam
复旦学报(自然科学版), 2005, (05) : 249 - 250
[24] The "optical" of nonlinear optical properties
Champagne, Benoit R.
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 248
[25] Experimental and theoretical studies of optical and nonlinear optical properties for MnTeMoO6 crystal
Jin, Chengguo
Wan, Mingjie
Huang, Lingxiong
Shao, Juxiang
Wang, Fanhou
JOURNAL OF ALLOYS AND COMPOUNDS, 2015, 651 : 585 - 589
[26] Dual experimental and computational approach for study of optical and nonlinear optical properties of naphthalimide derivatives
Santosh Kumar
Shabbir Muhammad
Abdullah G. Al-Sehemi
Saleh S. Alarfaji
Jay Singh
H. Algarni
Joonseok Koh
Chemical Papers, 2023, 77 : 4369 - 4378
[27] Experimental and computational study of naphthalimide derivatives: Synthesis, optical, nonlinear optical and antiviral properties
Kumar, Santosh
Muhammad, Shabbir
Alarfaji, Saleh S.
Yoon, Sanghyun
Kim, Minse
Youm, Keechul
Khalid, Muhammad
Chaudhry, Aijaz Rasool
Koh, Joonseok
OPTIK, 2021, 246
[28] Dual experimental and computational approach for study of optical and nonlinear optical properties of naphthalimide derivatives
Kumar, Santosh
Muhammad, Shabbir
Al-Sehemi, Abdullah G.
Alarfaji, Saleh S.
Singh, Jay
Algarni, H.
Koh, Joonseok
CHEMICAL PAPERS, 2023, 77 (08) : 4369 - 4378
[29] Vibrational and NMR properties of polyynes
Haque, Md. Mahbubul
Yin, Lichang
Nugraha, Ahmad R. T.
Saito, Riichiro
CARBON, 2011, 49 (10) : 3340 - 3345
[30] MATHEMATICAL INTERPRETATION OF EXPERIMENTAL RESEARCH RESULTS ON NONLINEAR OPTICAL MATERIAL PROPERTIES
Starkov, V. N.
Brodyn, M. S.
Tomchuk, P. M.
Gayvoronsky, V. Ya
Boyarchuk, A. Yu
UKRAINIAN JOURNAL OF PHYSICS, 2015, 60 (07): : 601 - 613

← 1 2 3 4 5 →