Nonlinear Optical Properties of Polyynes: An Experimental Prediction for Carbyne

被引：31
作者：
Agarwal, Nisha R. [1 ,5 ]
Lucotti, Andrea [1 ]
Tommasini, Matteo [1 ]
Chalifoux, Wesley A. [2 ]
Tykwinski, Rik R. [3 ,4 ]
机构：
[1] Politecn Milan, Dipartimento Chim Mat & Ingn Chim Giulio Natta, Piazza Leonardo da Vinci 32, I-20133 Milan, Italy
[2] Univ Nevada, Dept Chem, Reno, NV 89557 USA
[3] Univ Erlangen Nurnberg, Dept Chem & Pharm, Henkestr 42, D-91054 Erlangen, Germany
[4] Univ Erlangen Nurnberg, ICMM, Henkestr 42, D-91054 Erlangen, Germany
[5] Chalmers Univ Technol, S-41296 Gothenburg, Sweden
来源：
JOURNAL OF PHYSICAL CHEMISTRY C | 2016年 / 120卷 / 20期
基金：
加拿大自然科学与工程研究理事会;
关键词：
EFFECTIVE CONJUGATION LENGTH; RAMAN-SPECTROSCOPY; CARBON CHAINS; ORGANIC MATERIALS; CAPPED POLYYNES; LASER-ABLATION; HYPERPOLARIZABILITY; MOLECULES; OLIGOMERS; MODEL;
D O I：
10.1021/acs.jpcc.6b03071
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
We present the experimental determination of the vibrational contribution to molecular second hyperpolarizability (gamma(vib)) of very long polyynes that have been recently made available thanks to progress in chemical synthesis. Based on a simple theoretical model, the available experimental data allow estimating the asymptotic behavior of the vibrational contribution to molecular hyperpolarizability for increasing chain length.
引用
收藏
页码：11131 / 11139
页数：9
相关论文
共 95 条
  • [1] Structure and chain polarization of long polyynes investigated with infrared and Raman spectroscopy
    Agarwal, N. R.
    Lucotti, A.
    Fazzi, D.
    Tommasini, M.
    Castiglioni, C.
    Chalifoux, W. A.
    Tykwinski, R. R.
    [J]. JOURNAL OF RAMAN SPECTROSCOPY, 2013, 44 (10) : 1398 - 1410
  • [2] A novel methodology for the synthesis of complexes containing long carbon chains linking metal centres:: molecular structures of {Ru(dppe)Cp*}2(μ-C14) and {Co3(μ-dppm)(CO)7}2(μ3:μ3-C16)
    Antonova, AB
    Bruce, MI
    Elis, BG
    Gaudio, M
    Humphrey, PA
    Jevric, M
    Melino, G
    Nicholson, BK
    Perkins, GJ
    Skelton, BW
    Stapleton, B
    White, AH
    Zaitseva, NN
    [J]. CHEMICAL COMMUNICATIONS, 2004, (08) : 960 - 961
  • [3] Spectral dependence of nonlinear optical properties of symmetrical octatetraynes with p-substituted phenyl end-groups
    Arendt, Agata
    Kolkowski, Radoslaw
    Samoc, Marek
    Szafert, Slawomir
    [J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2015, 17 (20) : 13680 - 13688
  • [4] Bae S, 2010, NAT NANOTECHNOL, V5, P574, DOI [10.1038/NNANO.2010.132, 10.1038/nnano.2010.132]
  • [5] Baker G. A., 1996, PADE APPROXIMANTS XD
  • [6] Dangerously seeking linear carbon
    Baughman, RH
    [J]. SCIENCE, 2006, 312 (5776) : 1009 - 1010
  • [7] 3RD-ORDER NONLINEAR-OPTICAL RESPONSE IN ORGANIC MATERIALS - THEORETICAL AND EXPERIMENTAL ASPECTS
    BREDAS, JL
    ADANT, C
    TACKX, P
    PERSOONS, A
    PIERCE, BM
    [J]. CHEMICAL REVIEWS, 1994, 94 (01) : 243 - 278
  • [8] Bubeck C., 1998, ELECT MAT OLIGOMER A
  • [9] NONLINEAR OPTICAL STUDIES OF GRADED ENYNE OLIGOMERS
    BYRNE, HJ
    BLAU, W
    GIESA, R
    SCHULZ, RC
    [J]. CHEMICAL PHYSICS LETTERS, 1990, 167 (05) : 484 - 489
  • [10] Stabilization of linear carbon structures in a solid Ag nanoparticle assembly
    Casari, C. S.
    Russo, V.
    Li Bassi, A.
    Bottani, C. E.
    Cataldo, F.
    Lucotti, A.
    Tommasini, M.
    Del Zoppo, M.
    Castiglioni, C.
    Zerbi, G.
    [J]. APPLIED PHYSICS LETTERS, 2007, 90 (01)
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