Synthesis, structures, and luminescence of lanthanide coordination polymers constructed from benzimidazole-5,6-dicarboxylate and oxalate ligands

被引：19

作者：

Sun, Ya-Guang ^{[1
]}

Yu, Wan ^{[1
]}

Wang, Lei ^{[1
]}

Rong, Shu-Ting ^{[1
]}

Wu, Yong-Li ^{[1
]}

Ding, Fu ^{[1
]}

Zhang, Wan-Zhong ^{[1
]}

Gao, En-Jun ^{[1
]}

机构：

[1] Shenyang Inst Chem Technol, Lab Coordinat Chem, Shenyang 110142, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2010年 / 13卷 / 04期

关键词：

Hydrothermal synthesis; Coordination polymers; Crystal structure; Luminescence; HYDROTHERMAL SYNTHESIS; CRYSTAL; COMPLEXES; ACID; LN; ZINC(II); MN(II); TB; EU; ER;

D O I：

10.1016/j.inoche.2010.01.013

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Three novel coordination polymers [(Eu-2(Hbidc)(2)(ox)(2)center dot(H2O)(3)] (1), [Tb-2(Hbidc)(2)(ox)(H2O)(2)]center dot 4H(2)O (2), [Er-2(Hbidc)(2)(ox)] (3) have been synthesized with hydrothermal reaction (H(3)bidc = Benzimidazole-5,6-dicarboxylic acid, H(2)ox = Oxalic acid) and characterized by elemental analysis, IR and X-ray single crystal diffraction. 1, 2 and 3 have the same crystal system of triclinic, but they exhibit different kinds of metal-organic framework structures. The luminescent properties of 1 and 2 were studied at room temperature. (c) 2010 Elsevier B.V. All rights reserved.

引用

页码：479 / 483

页数：5

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