Developments of Corey-Chaykovsky in Organic Reactions and Total Synthesis of Natural Products

被引：31

作者：

Heravi, Majid M. ^{[1
]}

Asadi, Shima ^{[1
]}

Nazari, Niousha ^{[1
]}

Lashkariani, Boshra Malekzadeh ^{[1
]}

机构：

[1] Alzahra Univ, Dept Chem, Tehran, Iran

来源：

CURRENT ORGANIC SYNTHESIS | 2016年 / 13卷 / 03期

关键词：

Corey-Chaykovsky; epoxidation; dimethylsulfoxonium methylide; dimethylsulfonium methylide; organic and total synthesis; 2,2-DISUBSTITUTED TERMINAL EPOXIDES; YLIDE-MEDIATED EPOXIDATION; SULFUR YLIDES; ASYMMETRIC-SYNTHESIS; ENANTIOSELECTIVE SYNTHESIS; DIMETHYLOXOSULFONIUM METHYLIDE; DIASTEREOSELECTIVE AZIRIDINATION; DIMETHYLSULFOXONIUM METHYLIDE; CARBONYL-COMPOUNDS; SCALABLE SYNTHESIS;

D O I：

10.2174/1570179412666150710182304

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reactions of sulfur ylides with carbonyl, olefin or imine compounds named as the Corey-Chaykovsky, provide oxiranes, cyclopropane or aziridine, respectively. In this report, we try to introduce this important name reaction and highlight a comprehensive overview on the applications of this useful reaction in synthetic organic chemistry and total synthesis of natural products.

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页码：308 / 333

页数：26

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