Supported ionic liquid phase catalysis with supercritical flow

被引：66

作者：

Hintermair, Ulrich

Zhao, Guoying

Santini, Catherine C.

Muldoon, Mark J.

Cole-Hamilton, David J. ^{[1
]}

机构：

[1] Univ St Andrews, Sch Chem, EaStCHEM, St Andrews KY16 9ST, Fife, Scotland

[2] CNRS, Lab Chim Organomet Surface, UMR 9986, CPE Lyon, F-69616 Villeurbanne, France

来源：

CHEMICAL COMMUNICATIONS | 2007年 / 14期

关键词：

D O I：

10.1039/b616186c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Rapid hydroformylation of 1-octene (rates up to 800 h(-1)) with the catalyst remaining stable for at least 40 h and with very low rhodium leaching levels (0.5 ppm) is demonstrated when using a system involving flowing the substrate, reacting gases and products dissolved in supercritical CO2 (scCO(2)) over a fixed bed supported ionic liquid phase catalyst.

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页码：1462 / 1464

页数：3

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