Oxalic acid as the in situ carbon monoxide generator in palladium-catalyzed hydroxycarbonylation of arylhalides

被引：36
|
作者：
Shao, Changdong [1 ,2 ]
Lu, Ailan [1 ]
Wang, Xiaoling [1 ]
Zhou, Bo [1 ]
Guan, Xiaohong [2 ,3 ]
Zhang, Yanghui [1 ,2 ,4 ]
机构：
[1] Tongji Univ, Sch Chem Sci & Engn, 1239 Siping Rd, Shanghai 200092, Peoples R China
[2] Tongji Univ, UNEP Tongji Inst Environm Sustainable Dev, 1239 Siping Rd, Shanghai 200092, Peoples R China
[3] Tongji Univ, Coll Environm Sci & Engn, 1239 Siping Rd, Shanghai 200092, Peoples R China
[4] Shanghai Key Lab Chem Assessment & Sustainabil, 1239 Siping Rd, Shanghai 200092, Peoples R China
来源：
ORGANIC & BIOMOLECULAR CHEMISTRY | 2017年 / 15卷 / 23期
基金：
中国国家自然科学基金;
关键词：
KHAND-TYPE REACTION; LARGE-SCALE APPLICATIONS; ARYL HALIDES; EX-SITU; CARBONYLATION REACTIONS; COUPLING REACTIONS; N-FORMYLSACCHARIN; ORGANIC HALIDES; CO; CARBOXYLATION;
D O I：
10.1039/c7ob01052d
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An efficient palladium-catalyzed hydroxycarbonylation reaction of arylhalides using oxalic acid as a CO source has been developed. The reaction features high safety, low catalyst loading, and a broad substrate scope, and provides a safe and tractable approach to access a variety of aromatic carboxylic acid compounds. Mechanistic studies revealed the decomposition pattern of oxalic acid.
引用
收藏
页码：5033 / 5040
页数：8
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