Molecular structure of di-tert-butylamine-containing the monoedge-functionalized clathrochelate iron(II) tris-dioximate

被引：4
作者：
Burdukov, A. B. [1 ]
Pervukhina, N. V.
Vershinin, M. A.
Voloshin, Ya. Z.
机构：
[1] Russian Acad Sci, AV Nikolaev Inst Inorgan Chem, Siberian Div, Novosibirsk, Russia
[2] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, Moscow, Russia
来源：
JOURNAL OF STRUCTURAL CHEMISTRY | 2007年 / 48卷 / 02期
基金：
俄罗斯基础研究基金会;
关键词：
clathrochelates; iron(II); structures;
D O I：
10.1007/s10947-007-0053-5
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The structure of 1,8-bis(fluoroboro)-2,7,9,14,15,20-hexaoxa-3,6,10,13,16,19-hexaaza-4,5,11,12-tetraphenyl-17,18-bise(tert-butylamino)-bicyclo[6.6.6]eicosa-3,5,10,12,16,18-hexaene(2-)iron(2+) tris-dioximate clathrochelate was determined by X-ray diffraction (XRD) analysis. The compound has a molecular structure and crystallizes as triclinic crystals: a = 10.7673(2) angstrom, b = 11.9520(4) angstrom, c = 22.5473(7) angstrom, alpha = 75.729(l)degrees, beta = 89.161(l)degrees, gamma = 65.334(l)degrees, V = 2542.64(13) angstrom(3), Z = 2, space group P (1) over bar.
引用
收藏
页码：358 / 361
页数：4
相关论文
共 11 条
  • [1] Allen F.H., 1993, CHEM AUTOMAT NEWS, V8, P31
  • [2] [Anonymous], CAMBRIDGE STRUCTURAL
  • [3] [Anonymous], 1997, SHELXL 97 SHELXS 97
  • [4] Bruker AXS Inc, 2004, APEX2 (Version 1.08), SAINT (Version 7.03), and SADABS (Version 2.11)
  • [5] BURDUKOV AB, 2005, IZV RASS AKAD NAUK K, P1097
  • [6] SIR2004:: an improved tool for crystal structure determination and refinement
    Burla, MC
    Caliandro, R
    Camalli, M
    Carrozzini, B
    Cascarano, GL
    De Caro, L
    Giacovazzo, C
    Polidori, G
    Spagna, R
    [J]. JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2005, 38 : 381 - 388
  • [7] Kramer R., 2002, CLATHROCHELATES SYNT
  • [8] Mathews C K., 1996, Biochemistry
  • [9] Prediction of the geometry of low-spin iron(II) complexes using a modified concept of partial quadrupole splitting (PQS): Advantages and limitations
    Voloshin, YZ
    Polshin, EV
    Nazarenko, AY
    [J]. HYPERFINE INTERACTIONS, 2002, 141 (1-4): : 309 - 320
  • [10] Reactions of chloride iron(II) clathrochelates with aliphatic amines: an unexpected influence of the nature of the amine and solvent on the reaction products
    Voloshin, YZ
    Zavodnik, VE
    Varzatskii, OA
    Belsky, VK
    Vorontsov, II
    Antipin, MY
    [J]. INORGANICA CHIMICA ACTA, 2001, 321 (1-2) : 116 - 134
12