Nonprecious metal's graphene-supported electrocatalysts for hydrogen evolution reaction: Fundamentals to applications

被引:178
作者
Ali, Asad [1 ,2 ]
Shen, Pei Kang [1 ,2 ]
机构
[1] Guangxi Univ, Collaborat Innovat Ctr Sustainable Energy Mat, Guangxi Key Lab Electrochem Energy Mat, Nanning, Peoples R China
[2] Guangxi Univ, State Key Lab Proc Nonferrous Met & Featured Mat, Nanning, Peoples R China
关键词
graphene; hydrogen evolution reaction; nonprecious metal electrocatalysts; water splitting; NITROGEN-DOPED GRAPHENE; HIGHLY EFFICIENT ELECTROCATALYSTS; HIGH-PERFORMANCE; OXYGEN REDUCTION; ACTIVE ELECTROCATALYST; STABLE ELECTROCATALYST; ULTRATHIN NANOSHEETS; OXIDE NANOCOMPOSITE; CATALYTIC-ACTIVITY; HYBRID CATALYSTS;
D O I
10.1002/cey2.26
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Sustainable production of hydrogen is a hopeful requirement of a strategic future economy and development. Water splitting driven by electricity is a favorable pathway for renewable hydrogen production. This critical review highlighted recent efforts toward the development of the nanoscale synthesis of nonprecious metal's graphene-supported electrocatalysts and their electrocatalytic features for remarkable hydrogen evolution reaction (HER). Different essential nonprecious metal's graphene-supported electrocatalysts, including metal carbides, sulfides, phosphides, selenides, oxides, and nitrides are reviewed. In the exploration, attention is given to the strategies of activity enhancement, the synthetic approach, and the composition/structure electrocatalytic-performance relationship of these HER electrocatalysts. We are hopeful that this review confers a new momentum to the rational design of remarkable performance nonprecious metal's graphene-supported electrocatalysts and comprehensive guide for researchers to utilize the subject catalysts in regular water splitting.
引用
收藏
页码:99 / 121
页数:23
相关论文
共 102 条
[1]   Molybdenum-Based Carbon Hybrid Materials to Enhance the Hydrogen Evolution Reaction [J].
Bae, Seo-Yoon ;
Jeon, In-Yup ;
Mahmood, Javeed ;
Baek, Jong-Beom .
CHEMISTRY-A EUROPEAN JOURNAL, 2018, 24 (69) :18158-18179
[2]   Heavily Doped and Highly Conductive Hierarchical Nanoporous Graphene for Electrochemical Hydrogen Production [J].
Chen, Linghan ;
Han, Jiuhui ;
Ito, Yoshikazu ;
Fujita, Takeshi ;
Huang, Gang ;
Hu, Kailong ;
Hirata, Akihiko ;
Watanabe, Kentaro ;
Chen, Mingwei .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2018, 57 (40) :13302-13307
[3]   Molybdenum sulfide clusters-nitrogen-doped graphene hybrid hydrogel film as an efficient three-dimensional hydrogen evolution electrocatalyst [J].
Chen, Sheng ;
Duan, Jingjing ;
Tang, Youhong ;
Jin, Bo ;
Qiao, Shi Zhang .
NANO ENERGY, 2015, 11 :11-18
[4]   Tungsten Carbide-Nitride on Graphene Nanoplatelets as a Durable Hydrogen Evolution Electrocatalyst [J].
Chen, Wei-Fu ;
Schneider, Jonathan M. ;
Sasaki, Kotaro ;
Wang, Chiu-Hui ;
Schneider, Jacob ;
Iyer, Shilpa ;
Iyer, Shweta ;
Zhu, Yimei ;
Muckerman, James T. ;
Fujita, Etsuko .
CHEMSUSCHEM, 2014, 7 (09) :2414-2418
[5]   Biomass-derived electrocatalytic composites for hydrogen evolution [J].
Chen, Wei-Fu ;
Iyer, Shilpa ;
Iyer, Shweta ;
Sasaki, Kotaro ;
Wang, Chiu-Hui ;
Zhu, Yimei ;
Muckerman, James T. ;
Fujita, Etsuko .
ENERGY & ENVIRONMENTAL SCIENCE, 2013, 6 (06) :1818-1826
[6]   Superior electrocatalysis for hydrogen evolution with crumpled graphene/tungstendisulfide/tungsten trioxide ternary nanohybrids [J].
Chen, Yantao ;
Ren, Ren ;
Wen, Zhenhai ;
Ci, Suqin ;
Chang, Jingbo ;
Mao, Shun ;
Chen, Junhong .
NANO ENERGY, 2018, 47 :66-73
[7]   Oriented Transformation of Co-LDH into 2D/3D ZIF-67 to Achieve Co-N-C Hybrids for Efficient Overall Water Splitting [J].
Chen, Ziliang ;
Ha, Yuan ;
Jia, Huaxian ;
Yan, Xiaoxiao ;
Chen, Mao ;
Liu, Miao ;
Wu, Renbing .
ADVANCED ENERGY MATERIALS, 2019, 9 (19)
[8]   Ultrafine Co Nanoparticles Encapsulated in Carbon-Nanotubes-Grafted Graphene Sheets as Advanced Electrocatalysts for the Hydrogen Evolution Reaction [J].
Chen, Ziliang ;
Wu, Renbing ;
Liu, Yang ;
Ha, Yuan ;
Guo, Yanhui ;
Sun, Dalin ;
Liu, Miao ;
Fang, Fang .
ADVANCED MATERIALS, 2018, 30 (30)
[9]   Directional Construction of Vertical Nitrogen-Doped 1T-2H MoSe2/Graphene Shell/Core Nanoflake Arrays for Efficient Hydrogen Evolution Reaction [J].
Deng, Shengjue ;
Zhong, Yu ;
Zeng, Yinxiang ;
Wang, Yadong ;
Yao, Zhujun ;
Yang, Fan ;
Lin, Shiwei ;
Wang, Xiuli ;
Lu, Xihong ;
Xia, Xinhui ;
Tu, Jiangping .
ADVANCED MATERIALS, 2017, 29 (21)
[10]   Advanced catalyst supports for PEM fuel cell cathodes [J].
Du, Lei ;
Shao, Yuyan ;
Sun, Junming ;
Yin, Geping ;
Liu, Jun ;
Wang, Yong .
NANO ENERGY, 2016, 29 :314-322