A ruthenium nanocatalyst for the atmospheric hydrogenation of 1,5-cyclooctadiene

被引：2
|
作者：
Liu, Chuanchao [1 ]
Wang, Yanhua [1 ]
机构：
[1] Dalian Univ Technol, State Key Lab Fine Chem, 2 Linggong Rd, Dalian 116024, Peoples R China
来源：
JOURNAL OF CHEMICAL RESEARCH | 2022年 / 46卷 / 02期
基金：
中国国家自然科学基金;
关键词：
atmospheric hydrogen pressure; 1; 5-COD; Ru nanocatalyst; selective hydrogenation; thermoregulated phase-transfer catalysis; STABILIZED PALLADIUM NANOPARTICLES; SELECTIVE HYDROGENATION; HOMOGENEOUS HYDROGENATION; RECYCLABLE CATALYST; SOLVENT-FREE; NANOTUBES; BEHAVIOR; SYSTEM;
D O I：
10.1177/17475198221092945
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A ruthenium nanocatalyst is utilized for the first time for the highly efficient and selective hydrogenation of 1,5-cyclooctadiene under atmospheric hydrogen pressure. Under the optimized reaction conditions, the conversion of 1,5-cyclooctadiene and the selectivity for cyclooctene are >99% and 95%, respectively. The turnover frequency is 451 h(-1), which is higher than that ever reported for Ru complex catalysts.
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页数：5
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