Anticatalytic Strategies to Suppress Water Electrolysis in Aqueous Batteries

被引:255
作者
Sui, Yiming [1 ]
Ji, Xiulei [1 ]
机构
[1] Oregon State Univ, Dept Chem, Corvallis, OR 97331 USA
基金
美国国家科学基金会;
关键词
OXYGEN EVOLUTION REACTION; HIGH-ENERGY-DENSITY; LITHIUM-ION BATTERY; ELECTROCATALYTIC HYDROGEN EVOLUTION; DOPED ACTIVATED CARBON; PRUSSIAN BLUE ANALOG; IN-SALT ELECTROLYTE; HIGH-VOLTAGE; ELECTROCHEMICAL-BEHAVIOR; CORROSION BEHAVIOR;
D O I
10.1021/acs.chemrev.1c00191
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Aqueous electrolytes are the leading candidate to meet the surging demand for safe and low-cost storage batteries. Aqueous electrolytes facilitate more sustainable battery technologies due to the attributes of being nonflammable, environmentally benign, and cost effective. Yet, water's narrow electrochemical stability window remains the primary bottleneck for the development of high-energy aqueous batteries with long cycle life and infallible safety. Water's electrolysis leads to either hydrogen evolution reaction (HER) or oxygen evolution reaction (OER), which causes a series of dire consequences, including poor Coulombic efficiency, short device longevity, and safety issues. These are often showstoppers of a new aqueous battery technology besides the low energy density. Prolific progress has been made in the understanding of HER and OER from both catalysis and battery fields. Unfortunately, a systematic review on these advances from a battery chemistry standpoint is lacking. This review provides in-depth discussions on the mechanisms of water electrolysis on electrodes, where we summarize the critical influencing factors applicable for a broad spectrum of aqueous battery systems. Recent progress and existing challenges on suppressing water electrolysis are discussed, and our perspectives on the future development of this field are provided.
引用
收藏
页码:6654 / 6695
页数:42
相关论文
共 323 条
  • [1] Investigation of some parameters influencing electrocrystallisation of PbO2
    Abaci, S
    Pekmez, K
    Hökelek, T
    Yildiz, A
    [J]. JOURNAL OF POWER SOURCES, 2000, 88 (02) : 232 - 236
  • [2] Strategies to Improve the Performance of Carbon/Carbon Capacitors in Salt Aqueous Electrolytes
    Abbas, Q.
    Ratajczak, P.
    Babuchowska, P.
    Le Comte, A.
    Belanger, D.
    Brousse, T.
    Beguin, F.
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2015, 162 (05) : A5148 - A5157
  • [3] Corrosion inhibition of aluminum in hydrochloric acid by pyrazinamide derivatives
    Abdallah, M.
    Sobhi, M.
    Altass, H. M.
    [J]. JOURNAL OF MOLECULAR LIQUIDS, 2016, 223 : 1143 - 1150
  • [4] Electrochemical studies on the electrodeposited Zn-Ni-Co ternary alloy in different media
    Abou-Krisha, M. M.
    Rageh, H. M.
    Matter, E. A.
    [J]. SURFACE & COATINGS TECHNOLOGY, 2008, 202 (15) : 3739 - 3746
  • [5] Corrosion inhibition of zinc by calcium exchanged beidellite clay mineral: A new smart corrosion inhibitor
    Aghzzaf, A. Ait
    Rhouta, B.
    Rocca, E.
    Khalil, A.
    Steinmetz, J.
    [J]. CORROSION SCIENCE, 2014, 80 : 46 - 52
  • [6] Evaluation of the electrochemical activity of a Ti-RuO2-TiO2 permanent anode
    Aromaa, Jari
    Forsen, Olof
    [J]. ELECTROCHIMICA ACTA, 2006, 51 (27) : 6104 - 6110
  • [7] The Electronic Structure of the Vanadyl Ion
    Ballhausen, C. J.
    Gray, Harry B.
    [J]. INORGANIC CHEMISTRY, 1962, 1 (01) : 111 - 122
  • [8] A VALIDATED MATHEMATICAL-MODEL FOR A ZINC ELECTROWINNING CELL
    BARTON, GW
    SCOTT, AC
    [J]. JOURNAL OF APPLIED ELECTROCHEMISTRY, 1992, 22 (02) : 104 - 115
  • [9] Revised Pourbaix diagrams for zinc at 25-300 degrees C
    Beverskog, B
    Puigdomenech, I
    [J]. CORROSION SCIENCE, 1997, 39 (01) : 107 - 114
  • [10] Effect of mixed additives on lead-acid battery electrolyte
    Bhattacharya, A
    Basumallick, IN
    [J]. JOURNAL OF POWER SOURCES, 2003, 113 (02) : 382 - 387