Preparation of silver colloid by hydrochlorinated hydroxy amine method and its surface enhanced Raman substrate

被引:0
作者
Li, XL
Xu, WQ
Zhang, JH
Jia, HY
Zhao, B [1 ]
Yang, B
机构
[1] Jilin Univ, Key Lab Supermol Struct & Mat Educ Minist, Changchun 130023, Peoples R China
[2] Jilin Univ, Coll Chem, Changchun 130023, Peoples R China
来源
CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE | 2003年 / 24卷 / 04期
关键词
hydrochlorinated hydroxy amine; preparation; silver colloid; surface enhanced Raman spectroscopy;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new method hydrochlorinated hydroxy amine method for preparing silver colloid was reported, and the formation process of silver nanoparticles was studied by UV-Vis spectroscopy and TEM. From the results, we can see the particle formation process is as follows: small particles were formed at the beginning of the reaction, and then they aggregate to large ones rapidly, then the large particles decomposed to small ones gradually. The TEM images showed directly the same process as the results from the UV-Vis spectra, indicating that the particle size distribution became more and more uniform. In addition, we transferred the Ag nanoparticles to the glass slide by electrostatic interaction to produce SERS-active substrates. Strong SERS signals can be obtained on such substrates.
引用
收藏
页码:707 / 710
页数:4
相关论文
共 9 条
[1]  
Chen HF, 1999, CHEM J CHINESE U, V20, P620
[2]  
CHEN J, 1995, CHEM J CHINESE U, V16, P1697
[3]   Formation of silver nanoparticles and self-assembled two-dimensional ordered superlattice [J].
He, ST ;
Yao, JN ;
Jiang, P ;
Shi, DX ;
Zhang, HX ;
Xie, SS ;
Pang, SJ ;
Gao, HJ .
LANGMUIR, 2001, 17 (05) :1571-1575
[4]  
HIZAI H, 1974, J MACROMOL SCI CHEM, V13, P633
[5]  
Hu JW, 2002, CHEM J CHINESE U, V23, P123
[6]   ADSORPTION AND SURFACE-ENHANCED RAMAN OF DYES ON SILVER AND GOLD SOLS [J].
LEE, PC ;
MEISEL, D .
JOURNAL OF PHYSICAL CHEMISTRY, 1982, 86 (17) :3391-3395
[7]  
ULRICH N, 2000, LANGMUIR, V16, P9087
[8]  
Wang SL, 2002, CHEM J CHINESE U, V23, P1676
[9]  
XUE G, 1991, ANAL CHEM, V63, P2393