Direct observation of key reaction intermediates on gold clusters

被引：195

作者：

Stolcic, D

Fischer, M

Ganteför, G

Kim, YD ^{[1
]}

Sun, Q

Jena, P

机构：

[1] Univ Konstanz, Dept Phys, D-78457 Constance, Germany

[2] Virginia Commonwealth Univ, Dept Phys, Richmond, VA 23284 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2003年 / 125卷 / 10期

关键词：

D O I：

10.1021/ja0293406

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Using ultraviolet photoelectron spectroscopy, we provide direct experimental evidence that di-oxygen species are stable on anionic gold dimer and tetramer clusters at room temperature. The stabilization of molecular oxygen is crucial for the high activities of the low-temperature reactions on gold catalysts. Copyright © 2003 American Chemical Society.

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收藏

页码：2848 / 2849

页数：2

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