Synthesis and properties of novel star-shaped oligofluorene conjugated systems with BODIPY cores

被引:8
|
作者
Orofino-Pena, Clara [1 ]
Cortizo-Lacalle, Diego [1 ]
Cameron, Joseph [1 ]
Sajjad, Muhammad T. [2 ]
Manousiadis, Pavlos P. [2 ]
Findlay, Neil J. [1 ]
Kanibolotsky, L. [1 ,3 ]
Amarasinghe, Dimali [2 ]
Skabara, Peter J. [1 ]
Tuttle, Tell [1 ]
Turnbull, Graham A. [2 ]
Samuel, Ifor D. W. [2 ]
机构
[1] Univ Strathclyde, WestCHEM, Dept Pure & Appl Chem, Glasgow G1 1XL, Lanark, Scotland
[2] Univ St Andrews, Sch Phys & Astron, Organ Semicond Ctr, SUPA, St Andrews, NB KY16 9SS, Canada
[3] Inst Phys Organ Chem & Coal Chem, UA-83114 Donetsk, Ukraine
来源
基金
英国工程与自然科学研究理事会;
关键词
absorption spectroscopy; BODIPY; cyclic voltammetry; photoluminescence; star-shaped oligofluorene; ELECTROCHEMICAL PROPERTIES; MULTICHROMOPHORIC ARRAYS; COUPLING REACTIONS; DYES; DERIVATIVES; CHEMISTRY; DESIGN; RED;
D O I
10.3762/bjoc.10.285
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Star-shaped conjugated systems with varying oligofluorene arm length and substitution patterns of the central BODIPY core have been synthesised, leading to two families of compounds, T-B1-T-B4 and Y-B1-Y-B4, with T- and Y-shaped motifs, respectively. Thermal stability, cyclic voltammetry, absorption and photoluminescence spectroscopy of each member of these two families were studied in order to determine their suitability as emissive materials in photonic applications.
引用
收藏
页码:2704 / 2714
页数:11
相关论文
共 50 条
  • [11] SYNTHESIS AND PROPERTIES OF NOVEL STAR-SHAPED NYLON-6
    USUKI, A
    HASEGAWA, N
    OKADA, A
    KURAUCHI, T
    KOBUNSHI RONBUNSHU, 1995, 52 (09) : 576 - 581
  • [12] Synthesis and photophysical properties of star-shaped blue green emitting π-conjugated spirotruxenes
    Kotha, Sambasivarao
    Ali, Rashid
    Panguluri, Nageswara Rao
    Datta, Anindya
    Kannaujiya, Krishna K.
    TETRAHEDRON LETTERS, 2018, 59 (46) : 4080 - 4085
  • [13] Fluorescent Red-Emitting BODIPY Oligofluorene Star-Shaped Molecules as a Color Converter Material for Visible Light Communications
    Sajjad, Muhammad T.
    Manousiadis, Pavlos P.
    Orofino, Clara
    Cortizo-Lacalle, Diego
    Kanibolotsky, Alexander L.
    Rajbhandari, Sujan
    Amarasinghe, Dimali
    Chun, Hyunchae
    Faulkner, Grahame
    O'Brien, Dominic C.
    Skabara, Peter J.
    Turnbull, Graham A.
    Samuel, Ifor D. W.
    ADVANCED OPTICAL MATERIALS, 2015, 3 (04): : 536 - 540
  • [14] Novel star-shaped liquid crystal macromolecules based on conjugated structures of azo and Schiff bases: synthesis and properties
    Ge, Zhong-Xin
    Wang, Yi-Min
    Sun, Jiang-Tao
    Zhang, Zi-Yun
    Jia, Ying-Gang
    Tian, Mei
    Yao, Dan-Shu
    LIQUID CRYSTALS, 2023, 50 (15) : 2413 - 2433
  • [15] Controlled Synthesis and Supramolecular Organization of Conjugated Star-Shaped Polymers
    Van den Eede, Marie-Paule
    De Winter, Julien
    Gerbaux, Pascal
    Teyssandier, Joan
    De Feyter, Steven
    Van Goethem, Cedric
    Vankelecom, Ivo F. J.
    Koeckelberghs, Guy
    MACROMOLECULES, 2018, 51 (21) : 8689 - 8697
  • [16] Tetrathiafulvalene-oligofluorene star-shaped systems: new semiconductor materials for fluorescent moisture indicators
    Scanlan, Katrina
    Kanibolotsky, Alexander L.
    Breig, Benjamin
    Hedley, Gordon J.
    Skabara, Peter J.
    JOURNAL OF MATERIALS CHEMISTRY C, 2019, 7 (22) : 6582 - 6591
  • [17] Star-shaped conjugated compounds forming nematic discotic systems
    Meier, H
    Lehmann, M
    Holst, HC
    Schwöppe, D
    TETRAHEDRON, 2004, 60 (32) : 6881 - 6888
  • [18] Novel planar and star-shaped molecules: Synthesis, electrochemical and photophysical properties
    Niu, Qingfen
    Lu, Yunqiang
    Sun, Hongjian
    Li, Xiaoyan
    SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2013, 107 : 377 - 385
  • [19] Star-Shaped Silacyclobutene-Containing π-Systems: Synthesis and Optical Properties
    Liu, Junhui
    Zhang, Shaoguang
    Zhang, Wen-Xiong
    Xi, Zhenfeng
    ORGANOMETALLICS, 2009, 28 (02) : 413 - 417
  • [20] Synthesis and investigation of the properties of a star-shaped polysilane
    Chen, Ming
    Zhou, Bo
    Liao, Yijun
    Huang, Shiqiang
    MATERIALS LETTERS, 2009, 63 (23) : 2032 - 2034