Potential of Cellulose Functionalized with Carboxylic Acid as Biosorbent for the Removal of Cationic Dyes in Aqueous Solution

被引：47
作者：
Silva, Lucinaldo dos Santos [1 ]
Carvalho, Jhonatam de Oliveira [1 ]
de Sousa Bezerra, Roosevelt Delano [2 ]
da Silva, Mateus Soares [3 ]
Lustosa Ferreira, Francisco Jose [3 ]
Osajima, Josy Anteveli [3 ]
da Silva Filho, Edson Cavalcanti [3 ]
机构：
[1] IFMA, Fed Inst Maranhao, Acailandia Campus, BR-65930000 Acailandia, MA, Brazil
[2] IFPI, Fed Inst Piaui, Teresina Cent Campus, BR-64000040 Teresina, PI, Brazil
[3] Univ Fed Piaui, Interdisciplinary Lab Adv Mat LIMAV, BR-64049550 Teresina, PI, Brazil
来源：
MOLECULES | 2018年 / 23卷 / 04期
关键词：
cellulose; modification; description; adsorption; cationic dye; CRYSTAL VIOLET; MALACHITE GREEN; METHYLENE-BLUE; SUGARCANE BAGASSE; ADSORPTION; EQUILIBRIUM; SORPTION; ANHYDRIDE; KINETICS; THERMODYNAMICS;
D O I：
10.3390/molecules23040743
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
In the last decade, adsorption has been used to minimize the pollution caused by dyes, which represents a serious environmental problem. In this context, this work reports the preparation of phthalic anhydride-modified cellulose (PhCel), through the reaction of cellulose (Cel) with phthalic anhydride (Ph). The efficiency of the reaction was observed by elemental analysis, Fourier Transform Infrared (FTIR) spectroscopy, X-ray diffraction (XRD) and thermogravimetry/derivative thermogravimetry (TG/DTG). The adsorbent matrix (Cel and PhCel) was used in the removal of crystal violet (CV) and methylene blue (MB) dyes in aqueous medium. In the kinetic study, the experimental data obtained had the best fit to the pseudo-first-order model. In general, the isotherms obtained at different temperatures had a best fit to the model proposed by Langmuir, and the CV and MB adsorption process in adsorbent matrixes can be favored strictly by hydrogen bonds and/or electrostatic interactions for Cel and electrostatic interactions for PhCel.
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页数：14
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