Spectral studies of copper(II) complexes of 6-(3-thienyl) pyridine-2-thiosemicarbazone

被引：0

作者：

Mahjoub, Omima Abdalla ^{[1
]}

Farina, Yang ^{[1
]}

机构：

[1] Univ Kebangsaan Malaysia, Fac Sci & Technol, Sch Chem Sci & Food Technol, Ukm Bangi 43600, Selangor, Malaysia

来源：

2014 UKM FST POSTGRADUATE COLLOQUIUM: PROCEEDINGS OF THE UNIVERSITI KEBANGSAAN MALAYSIA, FACULTY OF SCIENCE AND TECHNOLOGY 2014 POSTGRADUATE COLLOQUIUM | 2014年 / 1614卷

关键词：

Thiosemicarbazone; Copper (II) complexes; Spectral studies; CRYSTAL-STRUCTURE; DNA CLEAVAGE; PALLADIUM(II) COMPLEXES; ANTIFUNGAL ACTIVITY; METAL-COMPLEXES; THIOSEMICARBAZONE; NICKEL(II); BINDING; BIS(THIOSEMICARBAZONE); CO;

D O I：

10.1063/1.4895193

中图分类号：

O59 [应用物理学];

学科分类号：

摘要：

Two novel copper(II) complexes [Cu(HL)Cl]Cl center dot H2O (1) and [Cu(L)NO3]center dot H2O (2) of the three NNS donor thiosemicarbazone ligand 6-(3-thienyl) pyridine -2-thiosemicarbazone have been synthesized. The ligand and its copper(II) complexes were characterized by elemental analysis (C, H, N, and S), FT-IR, UV-visible, magnetic susceptibility and molar conductance. The thiosemicarbazone is present either as the thione form in complex 1 or as thiol form in complex 2 and is coordinated to copper(II) atom via the pyridine nitrogen atom, the azomethine nitrogen atom and the sulfur atom. The physicochemical and spectral data suggest square planar geometry for copper(II) atoms.

引用

页码：186 / 191

页数：6

共 29 条

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