Facile synthesis of ultrathin Ni-MOF nanobelts for high-efficiency determination of glucose in human serum

被引：162

作者：

Xiao, Xiao ^{[1
]}

Zheng, Shasha ^{[1
]}

Li, Xinran ^{[1
]}

Zhang, Guangxun ^{[1
]}

Guo, Xiaotian ^{[1
]}

Xue, Huaiguo ^{[1
]}

Pang, Huan ^{[1
]}

机构：

[1] Yangzhou Univ, Sch Chem & Chem Engn, Inst Innovat Mat & Energy, Yangzhou 225002, Jiangsu, Peoples R China

来源：

JOURNAL OF MATERIALS CHEMISTRY B | 2017年 / 5卷 / 26期

基金：

中国国家自然科学基金;

关键词：

METAL-ORGANIC FRAMEWORKS; GRAPHENE OXIDE; NANOPARTICLES; FABRICATION; HYDROGELS; NANOSTRUCTURES; ELECTRODE; REDUCTION; COMPOSITE; PHASE;

D O I：

10.1039/c7tb00180k

中图分类号：

TB3 [工程材料学]; R318.08 [生物材料学];

学科分类号：

0805 ; 080501 ; 080502 ;

摘要：

Ultrathin Ni-MOF nanobelts, [Ni-20(C5H6O4)(20)( H2O)(8)]center dot 40H(2)O(Ni-MIL-77 NBs), were synthesized by a facile one-pot solution process and can be used as an efficient catalyst electrode for glucose oxidation under alkaline conditions. Electrochemical measurements demonstrate that the NB/GCE, when used as a non-enzymatic glucose sensor, offers superior analytical performances with a wide linear range ( from 1 mu M to 500 mu M), a low detection limit (0.25 mu M, signal-to-noise = 3), and a response sensitivity of 1.542 mu A mM(-1) cm(-2). Moreover, it can also be applied for glucose detection in human blood serum with the relative standard deviation (RSD) of 7.41%, showing the high precision of the sensor in measuring real samples.

引用

页码：5234 / 5239

页数：6

共 48 条

[1] 25th Anniversary Article: Rational Design and Applications of Hydrogels in Regenerative Medicine [J].

Annabi, Nasim ;

Tamayol, Ali ;

Uquillas, Jorge Alfredo ;

Akbari, Mohsen ;

Bertassoni, Luiz E. ;

Cha, Chaenyung ;

Camci-Unal, Gulden ;

Dokmeci, Mehmet R. ;

Peppas, Nicholas A. ;

Khademhosseini, Ali .

ADVANCED MATERIALS, 2014, 26 (01) :85-124

[2] Constructing heterostructure on highly roughened caterpillar-like gold nanotubes with cuprous oxide grains for ultrasensitive and stable nonenzymatic glucose sensor [J].

Chen, Anran ;

Ding, Yu ;

Yang, Zhimao ;

Yang, Shengchun .

BIOSENSORS & BIOELECTRONICS, 2015, 74 :967-973

[3] Fabrication of Core-Shell α-Fe2O3@Li4Ti5O12 Composite and Its Application in the Lithium Ion Batteries [J].

Chen, Ming ;

Li, Wei ;

Shen, Xiao ;

Diao, Guowang .

ACS APPLIED MATERIALS & INTERFACES, 2014, 6 (06) :4514-4523

[4] Three-Dimensional Ni2P Nanoarray: An Efficient Catalyst Electrode for Sensitive and Selective Nonenzymatic Glucose Sensing with High Specificity [J].

Chen, Tao ;

Liu, Danni ;

Lu, Wenbo ;

Wang, Kunyang ;

Du, Gu ;

Asiri, Abdullah M. ;

Sun, Xuping .

ANALYTICAL CHEMISTRY, 2016, 88 (16) :7885-7889

[5] An Efficient Synthesis Strategy for Metal-Organic Frameworks: Dry-Gel Synthesis of MOF-74 Framework with High Yield and Improved Performance [J].

Das, Atanu Kumar ;

Vemuri, Rama Sesha ;

Kutnyakov, Igor ;

McGrail, B. Peter ;

Motkuri, Radha Kishan .

SCIENTIFIC REPORTS, 2016, 6

[6] The fabrication and characterization of Cu-nanoparticle immobilization on a hybrid chitosan derivative-carbon support as a novel electrochemical sensor: application for the sensitive enzymeless oxidation of glucose and reduction of hydrogen peroxide [J].

Ensafi, Ali A. ;

Jafari-Asl, M. ;

Dorostkar, N. ;

Ghiaci, M. ;

Victoria Martinez-Huerta, M. ;

Fierro, J. L. G. .

JOURNAL OF MATERIALS CHEMISTRY B, 2014, 2 (06) :706-717

[7] The electrochemical study of glucose oxidase on gold-coated magnetic iron oxide nanoparticles [J].

Eskandari, Khadijeh ;

Zarei, Hajar ;

Ghourchian, Hedayatollah ;

Amoozadeh, Seyed-Mostafa .

JOURNAL OF ANALYTICAL CHEMISTRY, 2015, 70 (10) :1254-1260

[8] Silver Oxide Nanowalls Grown on Cu Substrate as an Enzymeless Glucose Sensor [J].

Fang, Bin ;

Gu, Aixia ;

Wang, Guangfeng ;

Wang, Wen ;

Feng, Yuehua ;

Zhang, Cuihong ;

Zhang, Xiaojun .

ACS APPLIED MATERIALS & INTERFACES, 2009, 1 (12) :2829-2834

[9] Simultaneous deposition of cerium oxide and gold nanostructures-characterization and analytical properties toward glucose electro-oxidation and sensing [J].

Gougis, Maxime ;

Pereira, Antonio ;

Ma, Dongling ;

Mohamedi, Mohamed .

RSC ADVANCES, 2014, 4 (75) :39955-39961

[10] Fe3O4/PANI/m-SiO2 as robust reactive catalyst supports for noble metal nanoparticles with improved stability and recyclability [J].

Han, Jie ;

Lu, Song ;

Jin, Chenjing ;

Wang, Minggui ;

Guo, Rong .

JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (32) :13016-13023

← 1 2 3 4 5 →