Control of the photoisomerization mode of carbon-carbon double bond by intramolecular hydrogen bond;: One-way photoisomerization of 2′-hydroxychalcone induced by adiabatic intramolecular hydrogen atom transfer

被引：23

作者：

Norikane, Y

Itoh, H

Arai, T ^{[1
]}

机构：

[1] Univ Tsukuba, Dept Chem, Tsukuba, Ibaraki 3058571, Japan

[2] Yamagata Univ, Dept Mat & Biol Chem, Yamagata 990856, Japan

来源：

CHEMISTRY LETTERS | 2000年 / 09期

关键词：

D O I：

10.1246/cl.2000.1094

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

To investigate the effect of intramolecular hydrogen bonding on the photoisomerization of carbon-carbon double bond, photoisomerization of 2'-hydroxychalcone has been studied. Based: on the quantum yield measurements and laser flash photolysis studies, it was found that 2'-hydroxychalcone isomerized only from cis- to trans-isomer. The one-way cia-trans isomerization is induced by the adiabatic hydrogen atom transfer in the triplet state.

引用

页码：1094 / 1095

页数：2

共 32 条

[31] The photoinduced hydrogen atom transfer and trans-cis isomerization of the C=C double bond in 1-(1-hydroxy-2-naphthyl)-3-(1-naphthyl)-2-propen-1-one and related compounds studied using nanosecond time-resolved infrared spectroscopy
Kaneda, K
Sato, S
Hamaguchi, H
Arai, T
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2004, 77 (08) : 1529 - 1535
[32] The photoinduced hydrogen atom transfer and trans-cis isomerization of the C=C double bond in 1-(1-hydroxy-2-naphthyl)-3-(1-naphthyl)-2-propen-1-one and related compounds studied using nanosecond time-resolved infrared spectroscopy
Arai, T. (arai@chem.tsukuba.ac.jp), 1600, Chemical Society of Japan (77):

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