Enhanced H2 Evolution on ZnIn2S4 Photocatalyst under Visible Light by Surface Modification with Metal Cyanoferrates

被引：15

作者：

Matsuoka, Hikaru ^{[1
]}

Higashi, Masanobu ^{[1
]}

Nakada, Akinobu ^{[1
]}

Tomita, Osamu ^{[1
]}

Abe, Ryu ^{[1
,2
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Nishikyo Ku, Kyoto 6158510, Japan

[2] JST CREST, Chiyoda Ku, 5 Sanbancho, Tokyo 1020075, Japan

来源：

CHEMISTRY LETTERS | 2018年 / 47卷 / 07期

关键词：

Photocatalyst; Water splitting; Metal sulfide; HYDROGEN-PRODUCTION; WATER; SULFIDE; IRRADIATION; MEDIATOR;

D O I：

10.1246/cl.180369

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The surface modification with zinc or indium cyanoferrate species was revealed to significantly increase the rate of H-2 evolution on Pt-loaded ZnIn2S4 photocatalyst under visible light in the presence of [Fe(CN)(6)](4-) as an electron donor basically due to the stable redox behavior, in addition to the previously reported cadmium cyanoferrate species. A stepwise modification was found to enable the formation of thin layers of such cyanoferrate on the photocatalyst surface and thereby improve further the rate of H-2 evolution.

引用

页码：941 / 944

页数：4

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